A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO2

Melis S. Duyar; Charlie Tsai; Jonathan L. Snider; Joseph A. Singh; Alessandro Gallo; Jong Suk Yoo; Andrew J. Medford; Frank Abild-Pedersen; Felix Studt; Jakob Kibsgaard; Stacey F. Bent; Jens K. Nørskov; Thomas F. Jaramillo

doi:10.1002/anie.201806583

A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO₂

Melis S. Duyar, Charlie Tsai, Jonathan L. Snider, Joseph A. Singh, Alessandro Gallo, Jong Suk Yoo, Andrew J. Medford, Frank Abild-Pedersen, Felix Studt, Jakob Kibsgaard, Stacey F. Bent, Jens K. Nørskov, Thomas F. Jaramillo

Department of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO₂/H₂ mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO₂. We present a molybdenum phosphide catalyst for CO and CO₂ reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO₂/H₂ feeds.

Original language	English
Pages (from-to)	15045-15050
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	46
DOIs	https://doi.org/10.1002/anie.201806583
State	Published - 12 Nov 2018

Keywords

CO hydrogenation
CO hydrogenation
formate
methanol synthesis
molybdenum phosphide

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Duyar, M. S., Tsai, C., Snider, J. L., Singh, J. A., Gallo, A., Yoo, J. S., Medford, A. J., Abild-Pedersen, F., Studt, F., Kibsgaard, J., Bent, S. F., Nørskov, J. K., & Jaramillo, T. F. (2018). A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO₂ Angewandte Chemie - International Edition, 57(46), 15045-15050. https://doi.org/10.1002/anie.201806583

@article{66be15ae1fb7491d92549f8f35eb3ce9,

title = "A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO2 ",

abstract = "Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO2/H2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO2. We present a molybdenum phosphide catalyst for CO and CO2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO2/H2 feeds.",

keywords = "CO hydrogenation, CO hydrogenation, formate, methanol synthesis, molybdenum phosphide",

author = "Duyar, \{Melis S.\} and Charlie Tsai and Snider, \{Jonathan L.\} and Singh, \{Joseph A.\} and Alessandro Gallo and Yoo, \{Jong Suk\} and Medford, \{Andrew J.\} and Frank Abild-Pedersen and Felix Studt and Jakob Kibsgaard and Bent, \{Stacey F.\} and N{\o}rskov, \{Jens K.\} and Jaramillo, \{Thomas F.\}",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = nov,

day = "12",

doi = "10.1002/anie.201806583",

language = "English",

volume = "57",

pages = "15045--15050",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

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Duyar, MS, Tsai, C, Snider, JL, Singh, JA, Gallo, A, Yoo, JS, Medford, AJ, Abild-Pedersen, F, Studt, F, Kibsgaard, J, Bent, SF, Nørskov, JK & Jaramillo, TF 2018, 'A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO₂ ', Angewandte Chemie - International Edition, vol. 57, no. 46, pp. 15045-15050. https://doi.org/10.1002/anie.201806583

TY - JOUR

T1 - A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO2

AU - Duyar, Melis S.

AU - Tsai, Charlie

AU - Snider, Jonathan L.

AU - Singh, Joseph A.

AU - Gallo, Alessandro

AU - Yoo, Jong Suk

AU - Medford, Andrew J.

AU - Abild-Pedersen, Frank

AU - Studt, Felix

AU - Kibsgaard, Jakob

AU - Bent, Stacey F.

AU - Nørskov, Jens K.

AU - Jaramillo, Thomas F.

PY - 2018/11/12

Y1 - 2018/11/12

N2 - Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO2/H2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO2. We present a molybdenum phosphide catalyst for CO and CO2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO2/H2 feeds.

AB - Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO2/H2 mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO2. We present a molybdenum phosphide catalyst for CO and CO2 reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO2/H2 feeds.

KW - CO hydrogenation

KW - formate

KW - methanol synthesis

KW - molybdenum phosphide

UR - https://www.scopus.com/pages/publications/85055261045

U2 - 10.1002/anie.201806583

DO - 10.1002/anie.201806583

M3 - Article

C2 - 30134041

AN - SCOPUS:85055261045

SN - 1433-7851

VL - 57

SP - 15045

EP - 15050

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 46

ER -

A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO₂

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