A new equation of state in hole theory based on a modified 's combinatorial factor

Mooho Hong; Jaeeon Chang; Hwayong Kim

doi:10.1016/s0378-3812(99)00101-6

A new equation of state in hole theory based on a modified 's combinatorial factor

Mooho Hong, Jaeeon Chang, Hwayong Kim

Department of Chemical Engineering

Seoul National University

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and two kinds of free volume expressions, two equations of state are derived, and are used to calculate the PVT behaviors of 10 pure polymer melts to test these EOS's. Good agreements between the theory and experimental data are obtained.

Original language	English
Pages (from-to)	293-301
Number of pages	9
Journal	Fluid Phase Equilibria
Volume	158-160
DOIs	https://doi.org/10.1016/s0378-3812(99)00101-6
State	Published - 1999
Event	Proceedings of the 1998 8th International Conference on Properties and Phase Equilibria for Product and Process Design - Noordwijkerhout, Netherlands Duration: 26 Apr 1998 → 1 May 1998

Keywords

Combinatorial factor
Equation of state
Free volume
Liquid state
PVT

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10.1016/s0378-3812(99)00101-6

Cite this

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title = "A new equation of state in hole theory based on a modified 's combinatorial factor",

abstract = "To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and two kinds of free volume expressions, two equations of state are derived, and are used to calculate the PVT behaviors of 10 pure polymer melts to test these EOS's. Good agreements between the theory and experimental data are obtained.",

keywords = "Combinatorial factor, Equation of state, Free volume, Liquid state, PVT",

author = "Mooho Hong and Jaeeon Chang and Hwayong Kim",

year = "1999",

doi = "10.1016/s0378-3812(99)00101-6",

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pages = "293--301",

journal = "Fluid Phase Equilibria",

issn = "0378-3812",

publisher = "Elsevier B.V.",

note = "Proceedings of the 1998 8th International Conference on Properties and Phase Equilibria for Product and Process Design ; Conference date: 26-04-1998 Through 01-05-1998",

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T1 - A new equation of state in hole theory based on a modified 's combinatorial factor

AU - Hong, Mooho

AU - Chang, Jaeeon

AU - Kim, Hwayong

PY - 1999

Y1 - 1999

N2 - To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and two kinds of free volume expressions, two equations of state are derived, and are used to calculate the PVT behaviors of 10 pure polymer melts to test these EOS's. Good agreements between the theory and experimental data are obtained.

AB - To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and two kinds of free volume expressions, two equations of state are derived, and are used to calculate the PVT behaviors of 10 pure polymer melts to test these EOS's. Good agreements between the theory and experimental data are obtained.

KW - Combinatorial factor

KW - Equation of state

KW - Free volume

KW - Liquid state

KW - PVT

UR - http://www.scopus.com/inward/record.url?scp=18544408391&partnerID=8YFLogxK

U2 - 10.1016/s0378-3812(99)00101-6

DO - 10.1016/s0378-3812(99)00101-6

M3 - Conference article

AN - SCOPUS:18544408391

SN - 0378-3812

VL - 158-160

SP - 293

EP - 301

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

T2 - Proceedings of the 1998 8th International Conference on Properties and Phase Equilibria for Product and Process Design

Y2 - 26 April 1998 through 1 May 1998

ER -

A new equation of state in hole theory based on a modified 's combinatorial factor

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Keywords

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