Abstract
In CO2 hydrogenation over Cu/ZrO2 based catalysts, the methanol formation activity could be correlated with copper dispersion. The reaction intermediates of methanol synthesis were carbonate, formate, formaldehyde and/or methoxy, and the rate determining step for methanol synthesis seems to be the conversion of formate into formaldehyde or methoxy.
Original language | English |
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Pages (from-to) | 505-508 |
Number of pages | 4 |
Journal | Studies in Surface Science and Catalysis |
Volume | 114 |
DOIs | |
State | Published - 1998 |