Analytical pyrolysis reaction characteristics of Porphyra tenera

Young Min Kim; Tae Uk Han; Boram Lee; Atsushi Watanabe; Norio Teramae; Jeong Hoon Kim; Young Kwon Park; Hyunwoong Park; Seungdo Kim

doi:10.1016/j.algal.2018.03.003

Analytical pyrolysis reaction characteristics of Porphyra tenera

Young Min Kim
, Tae Uk Han
, Boram Lee
, Atsushi Watanabe
, Norio Teramae
, Jeong Hoon Kim
, Young Kwon Park
, Hyunwoong Park
, Seungdo Kim

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The non-isothermal pyrolysis of red algae (Porphyra tenera) was studied via thermogravimetric (TG) analysis in combination with two types of analytical pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS) techniques, namely, evolved gas analysis (EGA)-MS and multi-shot Py-GC/MS. The TG and model-free kinetic analyses revealed that the pyrolysis of P. tenera proceeded via the independent decomposition of carbohydrates, proteins, and lipids. Differential TG and EGA-MS indicated the existence of three decomposition temperature regions. In the first temperature region (<300 °C), carbohydrates were mainly decomposed. Large amounts of pyrolyzates of proteins and lipids such as toluene, phenols, aromatic amino acids, and hexadecanoic acid were produced in the second temperature region (301–380 °C). In the third region (>380 °C), large amounts of aromatic hydrocarbons and alkanes were obtained by the secondary cracking of the pyrolyzates of proteins and lipids.

Original language	English
Pages (from-to)	60-69
Number of pages	10
Journal	Algal Research
Volume	32
DOIs	https://doi.org/10.1016/j.algal.2018.03.003
State	Published - Jun 2018

Keywords

Evolved gas analysis
Kinetic analysis
Multi-shot pyrolysis
Porphyra tenera
Toluene

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10.1016/j.algal.2018.03.003

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title = "Analytical pyrolysis reaction characteristics of Porphyra tenera",

abstract = "The non-isothermal pyrolysis of red algae (Porphyra tenera) was studied via thermogravimetric (TG) analysis in combination with two types of analytical pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS) techniques, namely, evolved gas analysis (EGA)-MS and multi-shot Py-GC/MS. The TG and model-free kinetic analyses revealed that the pyrolysis of P. tenera proceeded via the independent decomposition of carbohydrates, proteins, and lipids. Differential TG and EGA-MS indicated the existence of three decomposition temperature regions. In the first temperature region (<300 °C), carbohydrates were mainly decomposed. Large amounts of pyrolyzates of proteins and lipids such as toluene, phenols, aromatic amino acids, and hexadecanoic acid were produced in the second temperature region (301–380 °C). In the third region (>380 °C), large amounts of aromatic hydrocarbons and alkanes were obtained by the secondary cracking of the pyrolyzates of proteins and lipids.",

keywords = "Evolved gas analysis, Kinetic analysis, Multi-shot pyrolysis, Porphyra tenera, Toluene",

author = "Kim, \{Young Min\} and Han, \{Tae Uk\} and Boram Lee and Atsushi Watanabe and Norio Teramae and Kim, \{Jeong Hoon\} and Park, \{Young Kwon\} and Hyunwoong Park and Seungdo Kim",

note = "Publisher Copyright: {\textcopyright} 2018",

year = "2018",

month = jun,

doi = "10.1016/j.algal.2018.03.003",

language = "English",

volume = "32",

pages = "60--69",

journal = "Algal Research",

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T1 - Analytical pyrolysis reaction characteristics of Porphyra tenera

AU - Kim, Young Min

AU - Han, Tae Uk

AU - Lee, Boram

AU - Watanabe, Atsushi

AU - Teramae, Norio

AU - Kim, Jeong Hoon

AU - Park, Young Kwon

AU - Park, Hyunwoong

AU - Kim, Seungdo

PY - 2018/6

Y1 - 2018/6

N2 - The non-isothermal pyrolysis of red algae (Porphyra tenera) was studied via thermogravimetric (TG) analysis in combination with two types of analytical pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS) techniques, namely, evolved gas analysis (EGA)-MS and multi-shot Py-GC/MS. The TG and model-free kinetic analyses revealed that the pyrolysis of P. tenera proceeded via the independent decomposition of carbohydrates, proteins, and lipids. Differential TG and EGA-MS indicated the existence of three decomposition temperature regions. In the first temperature region (<300 °C), carbohydrates were mainly decomposed. Large amounts of pyrolyzates of proteins and lipids such as toluene, phenols, aromatic amino acids, and hexadecanoic acid were produced in the second temperature region (301–380 °C). In the third region (>380 °C), large amounts of aromatic hydrocarbons and alkanes were obtained by the secondary cracking of the pyrolyzates of proteins and lipids.

AB - The non-isothermal pyrolysis of red algae (Porphyra tenera) was studied via thermogravimetric (TG) analysis in combination with two types of analytical pyrolyzer-gas chromatography/mass spectrometry (Py-GC/MS) techniques, namely, evolved gas analysis (EGA)-MS and multi-shot Py-GC/MS. The TG and model-free kinetic analyses revealed that the pyrolysis of P. tenera proceeded via the independent decomposition of carbohydrates, proteins, and lipids. Differential TG and EGA-MS indicated the existence of three decomposition temperature regions. In the first temperature region (<300 °C), carbohydrates were mainly decomposed. Large amounts of pyrolyzates of proteins and lipids such as toluene, phenols, aromatic amino acids, and hexadecanoic acid were produced in the second temperature region (301–380 °C). In the third region (>380 °C), large amounts of aromatic hydrocarbons and alkanes were obtained by the secondary cracking of the pyrolyzates of proteins and lipids.

KW - Evolved gas analysis

KW - Kinetic analysis

KW - Multi-shot pyrolysis

KW - Porphyra tenera

KW - Toluene

UR - https://www.scopus.com/pages/publications/85044118482

U2 - 10.1016/j.algal.2018.03.003

DO - 10.1016/j.algal.2018.03.003

M3 - Article

AN - SCOPUS:85044118482

SN - 2211-9264

VL - 32

SP - 60

EP - 69

JO - Algal Research

JF - Algal Research

ER -

Analytical pyrolysis reaction characteristics of Porphyra tenera

Abstract

Keywords

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