Catalytic copyrolysis of cork oak and waste plastic films over HBeta

Young Kwon Park; Boram Lee; Atsushi Watanabe; Hyung Won Lee; Ji Young Lee; Seungdo Kim; Tae Uk Han; Young Min Kim

doi:10.3390/catal8080318

Catalytic copyrolysis of cork oak and waste plastic films over HBeta

Young Kwon Park, Boram Lee, Atsushi Watanabe, Hyung Won Lee, Ji Young Lee, Seungdo Kim, Tae Uk Han, Young Min Kim

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The catalytic fast copyrolysis (CFCP) of cork oak (CoOak) and waste plastic films (WPFs) over HBeta(25) (SiO₂/Al₂O₃: 25) was investigated using a thermogravimetric (TG) analyzer and a tandem micro reactor-gas chromatography/mass spectrometry (TMR-GC/MS) to determine the effectiveness of WPFs as the hydrogen donating cofeeding feedstock on the CFCP of biomass. By applying CFCP, the maximum decomposition temperatures of CoOak (373.4 °C) and WPFs (487.9 °C) were reduced to 364.5 °C for CoOak and 436.5 °C for WPFs due to the effective interaction between the pyrolysis intermediates of CoOak and WPFs over HBeta(25), which has strong acidity and an appropriate pore size. The experimental yields of aromatic hydrocarbons on the CFCP of CoOak and WPFs were higher than their calculated yields concluded from the yields obtained from the individual catalytic fast pyrolysis (CFP) of CoOak and WPFs. The coke amount produced from the CFP of CoOak and WPFs over HBeta(25) were also decreased by applying CFCP.

Original language	English
Article number	318
Journal	Catalysts
Volume	8
Issue number	8
DOIs	https://doi.org/10.3390/catal8080318
State	Published - 3 Aug 2018

Keywords

Biomass
Catalytic copyrolysis
HBeta(25)
Waste plastic films

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title = "Catalytic copyrolysis of cork oak and waste plastic films over HBeta",

abstract = "The catalytic fast copyrolysis (CFCP) of cork oak (CoOak) and waste plastic films (WPFs) over HBeta(25) (SiO2/Al2O3: 25) was investigated using a thermogravimetric (TG) analyzer and a tandem micro reactor-gas chromatography/mass spectrometry (TMR-GC/MS) to determine the effectiveness of WPFs as the hydrogen donating cofeeding feedstock on the CFCP of biomass. By applying CFCP, the maximum decomposition temperatures of CoOak (373.4 °C) and WPFs (487.9 °C) were reduced to 364.5 °C for CoOak and 436.5 °C for WPFs due to the effective interaction between the pyrolysis intermediates of CoOak and WPFs over HBeta(25), which has strong acidity and an appropriate pore size. The experimental yields of aromatic hydrocarbons on the CFCP of CoOak and WPFs were higher than their calculated yields concluded from the yields obtained from the individual catalytic fast pyrolysis (CFP) of CoOak and WPFs. The coke amount produced from the CFP of CoOak and WPFs over HBeta(25) were also decreased by applying CFCP.",

keywords = "Biomass, Catalytic copyrolysis, HBeta(25), Waste plastic films",

author = "Park, {Young Kwon} and Boram Lee and Atsushi Watanabe and Lee, {Hyung Won} and Lee, {Ji Young} and Seungdo Kim and Han, {Tae Uk} and Kim, {Young Min}",

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doi = "10.3390/catal8080318",

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AU - Park, Young Kwon

AU - Lee, Boram

AU - Watanabe, Atsushi

AU - Lee, Hyung Won

AU - Lee, Ji Young

AU - Kim, Seungdo

AU - Han, Tae Uk

AU - Kim, Young Min

PY - 2018/8/3

Y1 - 2018/8/3

N2 - The catalytic fast copyrolysis (CFCP) of cork oak (CoOak) and waste plastic films (WPFs) over HBeta(25) (SiO2/Al2O3: 25) was investigated using a thermogravimetric (TG) analyzer and a tandem micro reactor-gas chromatography/mass spectrometry (TMR-GC/MS) to determine the effectiveness of WPFs as the hydrogen donating cofeeding feedstock on the CFCP of biomass. By applying CFCP, the maximum decomposition temperatures of CoOak (373.4 °C) and WPFs (487.9 °C) were reduced to 364.5 °C for CoOak and 436.5 °C for WPFs due to the effective interaction between the pyrolysis intermediates of CoOak and WPFs over HBeta(25), which has strong acidity and an appropriate pore size. The experimental yields of aromatic hydrocarbons on the CFCP of CoOak and WPFs were higher than their calculated yields concluded from the yields obtained from the individual catalytic fast pyrolysis (CFP) of CoOak and WPFs. The coke amount produced from the CFP of CoOak and WPFs over HBeta(25) were also decreased by applying CFCP.

AB - The catalytic fast copyrolysis (CFCP) of cork oak (CoOak) and waste plastic films (WPFs) over HBeta(25) (SiO2/Al2O3: 25) was investigated using a thermogravimetric (TG) analyzer and a tandem micro reactor-gas chromatography/mass spectrometry (TMR-GC/MS) to determine the effectiveness of WPFs as the hydrogen donating cofeeding feedstock on the CFCP of biomass. By applying CFCP, the maximum decomposition temperatures of CoOak (373.4 °C) and WPFs (487.9 °C) were reduced to 364.5 °C for CoOak and 436.5 °C for WPFs due to the effective interaction between the pyrolysis intermediates of CoOak and WPFs over HBeta(25), which has strong acidity and an appropriate pore size. The experimental yields of aromatic hydrocarbons on the CFCP of CoOak and WPFs were higher than their calculated yields concluded from the yields obtained from the individual catalytic fast pyrolysis (CFP) of CoOak and WPFs. The coke amount produced from the CFP of CoOak and WPFs over HBeta(25) were also decreased by applying CFCP.

KW - Biomass

KW - Catalytic copyrolysis

KW - HBeta(25)

KW - Waste plastic films

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Catalytic copyrolysis of cork oak and waste plastic films over HBeta

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