Catalytic cracking of LLDPE over MCM-48

Jong Ki Jeon, Hyun Ju Park, Jin Heong Yim, Ji Man Kim, Jinho Jung, Young Kwon Park

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

3 Scopus citations

Abstract

Applicability of Al-MCM-48 as a catalyst for the linear low density polyethylene (LLDPE) degradation was investigated using a thermogravimetric analyzer as well as a batch reactor. The degradation products were analyzed by GC/MS, GC-TCD and GC-FID. The activation energy of LLDPE degradation was lowered by the addition of Al-MCM-48. The oil and gas yields were higher over Al-MCM-48 than those over Si-MCM-48. Al-MCM-48 generated mainly C7-C 10 hydrocarbons, while Si-MCM-48 exhibited the relatively broader distribution of the oil products (C8-C14). Al-MCM-48 showed high catalytic stability for the LLDPE degradation.

Original languageEnglish
Title of host publicationAdvances in Nanomaterials and Processing - IUMRS - ICA - 2006 International Conference in Asia
PublisherTrans Tech Publications Ltd.
Pages1757-1760
Number of pages4
EditionPART 2
ISBN (Print)3908451310, 9783908451310
DOIs
StatePublished - 2007
EventIUMRS International Conference in Asia 2006, IUMRS-ICA 2006 - Jeju, Korea, Republic of
Duration: 10 Sep 200614 Sep 2006

Publication series

NameSolid State Phenomena
NumberPART 2
Volume124-126
ISSN (Print)1012-0394

Conference

ConferenceIUMRS International Conference in Asia 2006, IUMRS-ICA 2006
Country/TerritoryKorea, Republic of
CityJeju
Period10/09/0614/09/06

Keywords

  • Al-MCM-48
  • Catalytic degradation
  • Catalytic stability
  • LLDPE

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