Catalytic fast pyrolysis of wild reed over nanoporous SBA-15 catalysts

Y. K. Park; Myung Lang Yoo; Sung Hoon Park

doi:10.1166/jnn.2016.10979

Catalytic fast pyrolysis of wild reed over nanoporous SBA-15 catalysts

Y. K. Park, Myung Lang Yoo, Sung Hoon Park

School of Environmental Engineering

Sunchon National University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Wild reed was pyrolyzed over two nanoporous SBA-15 catalysts with different acid characteristics: Si-SBA-15 and Al-SBA-15. Al was grafted on Si-SBA-15 to increase the acidity and enhance the catalytic activity. Fast pyrolysis was carried out using a pyrolysis-gas chromatography/mass spectrometry system at 550°C for real-time analysis of the products. Significant improvement of the product bio-oil quality was attained by catalytic reforming over nanoporous Al-SBA-15. The fraction of total oxygenates was reduced because of the decrease in the fraction of ketones, aldehydes, and carboxylates, which deteriorate the fuel quality of bio-oil. On the other hand, the fractions of furans and aromatics, which are the chemicals with high value-added, were increased by the catalytic reforming. The catalytic activity of Al-SBA-15 was considerably higher than that of Si-SBA-15 because the incorporation of Al increased the catalyst acidity.

Original language	English
Pages (from-to)	4561-4564
Number of pages	4
Journal	Journal of Nanoscience and Nanotechnology
Volume	16
Issue number	5
DOIs	https://doi.org/10.1166/jnn.2016.10979
State	Published - 1 May 2016

Keywords

Catalytic pyrolysis
Nanoporous catalyst
SBA-15
Wild reed

Access to Document

10.1166/jnn.2016.10979

Cite this

@article{10d53d24b36c4625884abf00eada4e16,

title = "Catalytic fast pyrolysis of wild reed over nanoporous SBA-15 catalysts",

abstract = "Wild reed was pyrolyzed over two nanoporous SBA-15 catalysts with different acid characteristics: Si-SBA-15 and Al-SBA-15. Al was grafted on Si-SBA-15 to increase the acidity and enhance the catalytic activity. Fast pyrolysis was carried out using a pyrolysis-gas chromatography/mass spectrometry system at 550°C for real-time analysis of the products. Significant improvement of the product bio-oil quality was attained by catalytic reforming over nanoporous Al-SBA-15. The fraction of total oxygenates was reduced because of the decrease in the fraction of ketones, aldehydes, and carboxylates, which deteriorate the fuel quality of bio-oil. On the other hand, the fractions of furans and aromatics, which are the chemicals with high value-added, were increased by the catalytic reforming. The catalytic activity of Al-SBA-15 was considerably higher than that of Si-SBA-15 because the incorporation of Al increased the catalyst acidity.",

keywords = "Catalytic pyrolysis, Nanoporous catalyst, SBA-15, Wild reed",

author = "Park, {Y. K.} and Yoo, {Myung Lang} and Park, {Sung Hoon}",

year = "2016",

month = may,

day = "1",

doi = "10.1166/jnn.2016.10979",

language = "English",

volume = "16",

pages = "4561--4564",

journal = "Journal of Nanoscience and Nanotechnology",

issn = "1533-4880",

publisher = "American Scientific Publishers",

number = "5",

}

TY - JOUR

T1 - Catalytic fast pyrolysis of wild reed over nanoporous SBA-15 catalysts

AU - Park, Y. K.

AU - Yoo, Myung Lang

AU - Park, Sung Hoon

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Wild reed was pyrolyzed over two nanoporous SBA-15 catalysts with different acid characteristics: Si-SBA-15 and Al-SBA-15. Al was grafted on Si-SBA-15 to increase the acidity and enhance the catalytic activity. Fast pyrolysis was carried out using a pyrolysis-gas chromatography/mass spectrometry system at 550°C for real-time analysis of the products. Significant improvement of the product bio-oil quality was attained by catalytic reforming over nanoporous Al-SBA-15. The fraction of total oxygenates was reduced because of the decrease in the fraction of ketones, aldehydes, and carboxylates, which deteriorate the fuel quality of bio-oil. On the other hand, the fractions of furans and aromatics, which are the chemicals with high value-added, were increased by the catalytic reforming. The catalytic activity of Al-SBA-15 was considerably higher than that of Si-SBA-15 because the incorporation of Al increased the catalyst acidity.

AB - Wild reed was pyrolyzed over two nanoporous SBA-15 catalysts with different acid characteristics: Si-SBA-15 and Al-SBA-15. Al was grafted on Si-SBA-15 to increase the acidity and enhance the catalytic activity. Fast pyrolysis was carried out using a pyrolysis-gas chromatography/mass spectrometry system at 550°C for real-time analysis of the products. Significant improvement of the product bio-oil quality was attained by catalytic reforming over nanoporous Al-SBA-15. The fraction of total oxygenates was reduced because of the decrease in the fraction of ketones, aldehydes, and carboxylates, which deteriorate the fuel quality of bio-oil. On the other hand, the fractions of furans and aromatics, which are the chemicals with high value-added, were increased by the catalytic reforming. The catalytic activity of Al-SBA-15 was considerably higher than that of Si-SBA-15 because the incorporation of Al increased the catalyst acidity.

KW - Catalytic pyrolysis

KW - Nanoporous catalyst

KW - SBA-15

KW - Wild reed

UR - http://www.scopus.com/inward/record.url?scp=84970024522&partnerID=8YFLogxK

U2 - 10.1166/jnn.2016.10979

DO - 10.1166/jnn.2016.10979

M3 - Article

AN - SCOPUS:84970024522

SN - 1533-4880

VL - 16

SP - 4561

EP - 4564

JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

IS - 5

ER -

Catalytic fast pyrolysis of wild reed over nanoporous SBA-15 catalysts

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this