Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry

Jeong Wook Kim; Sung Hoon Park; Jinho Jung; Jong Ki Jeon; Chang Hyun Ko; Kwang Eun Jeong; Young Kwon Park

doi:10.1016/j.biortech.2013.03.062

Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry

Jeong Wook Kim
, Sung Hoon Park
, Jinho Jung
, Jong Ki Jeon
, Chang Hyun Ko
, Kwang Eun Jeong
, Young Kwon Park

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

45 Scopus citations

Abstract

In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO₂/Al₂O₃=23 and 80) and HBeta (SiO₂/Al₂O₃=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO₂/Al₂O₃ ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.

Original language	English
Pages (from-to)	431-436
Number of pages	6
Journal	Bioresource Technology
Volume	136
DOIs	https://doi.org/10.1016/j.biortech.2013.03.062
State	Published - May 2013

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Aromatics
Bio-oil
Catalytic pyrolysis
Mandarin residue
Metal

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10.1016/j.biortech.2013.03.062

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title = "Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry",

abstract = "In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO2/Al2O3=23 and 80) and HBeta (SiO2/Al2O3=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO2/Al2O3 ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.",

keywords = "Aromatics, Bio-oil, Catalytic pyrolysis, Mandarin residue, Metal",

author = "Kim, \{Jeong Wook\} and Park, \{Sung Hoon\} and Jinho Jung and Jeon, \{Jong Ki\} and Ko, \{Chang Hyun\} and Jeong, \{Kwang Eun\} and Park, \{Young Kwon\}",

year = "2013",

month = may,

doi = "10.1016/j.biortech.2013.03.062",

language = "English",

volume = "136",

pages = "431--436",

journal = "Bioresource Technology",

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T1 - Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry

AU - Kim, Jeong Wook

AU - Park, Sung Hoon

AU - Jung, Jinho

AU - Jeon, Jong Ki

AU - Ko, Chang Hyun

AU - Jeong, Kwang Eun

AU - Park, Young Kwon

PY - 2013/5

Y1 - 2013/5

N2 - In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO2/Al2O3=23 and 80) and HBeta (SiO2/Al2O3=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO2/Al2O3 ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.

AB - In this study, the catalytic pyrolysis of mandarin residue from the mandarin juice processing industry was carried out using pyrolysis gas chromatography/mass spectroscopy and employing microporous zeolite catalysts, HZSM-5 (SiO2/Al2O3=23 and 80) and HBeta (SiO2/Al2O3=25). The effect of acidity of the catalyst was investigated by comparing the activity of two HZSM-5 catalysts with different SiO2/Al2O3 ratios. The effect of catalyst structure was explored by comparing the results obtained using HZSM-5 (23) and HBeta. Most oxygenates produced from non-catalytic pyrolysis were removed by catalytic upgrading, whereas the yields of mono-aromatics, which are important feedstock materials for the chemical industry, increased considerably, improving the quality of the bio-oil produced. HZSM-5 (23), having the highest acidity among the catalysts used in this study, showed superior catalytic activity to those of HZSM-5 (80) and HBeta. Pt/HZSM-5 (23) and Ga/HZSM-5 (23) resulted in an even higher yield of aromatics.

KW - Aromatics

KW - Bio-oil

KW - Catalytic pyrolysis

KW - Mandarin residue

KW - Metal

UR - https://www.scopus.com/pages/publications/84876310197

U2 - 10.1016/j.biortech.2013.03.062

DO - 10.1016/j.biortech.2013.03.062

M3 - Article

AN - SCOPUS:84876310197

SN - 0960-8524

VL - 136

SP - 431

EP - 436

JO - Bioresource Technology

JF - Bioresource Technology

ER -

Catalytic pyrolysis of mandarin residue from the mandarin juice processing industry

Abstract

UN SDGs

Keywords

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