Catalytic pyrolysis of polystyrene and polyethylene terephthalate over Al-MSU-F

Daejun Oh; Hyung Won Lee; Young Min Kim; Young Kwon Park

doi:10.1016/j.egypro.2018.06.015

Catalytic pyrolysis of polystyrene and polyethylene terephthalate over Al-MSU-F

Daejun Oh, Hyung Won Lee, Young Min Kim, Young Kwon Park

School of Environmental Engineering

University of Seoul

Research output: Contribution to journal › Conference article › peer-review

25 Scopus citations

Abstract

Catalytic pyrolysis (CP) of waste plastic film over mesoporous catalyst, Al-MSU-F, was investigated using polystyrene (PS) and polyethylene terephthalate (PET) as the model plastic resins. Thermogravimetric analysis of PS and PET indicated that their decomposition temperatures were shifted to the much lower temperature owing to the high diffusion ability of reactant into mesopore of Al-MSU-F. Py-GC/MS analysis for the CP of PS and PET revealed that the large amount of aromatics can be obtained by the use of Al-MSU-F and it was further increased by using the higher catalyst/polymer ratio. CP products of PET over Al-MSU-F showed the high selectivity to mono aromatic hydrocarbons. Meanwhile, those of PS revealed the high selectivity to poly aromatics.

Original language	English
Pages (from-to)	111-117
Number of pages	7
Journal	Energy Procedia
Volume	144
DOIs	https://doi.org/10.1016/j.egypro.2018.06.015
State	Published - 2018
Event	4th International Symposium on Hydrogen Energy, Renewable Energy and Materials, HEREM 2018 - Bangkok, Thailand Duration: 13 Jun 2018 → 14 Jun 2018

Keywords

Al-MSU-F
Catalytic pyrolysis
PET
PS
Waste plastic films

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10.1016/j.egypro.2018.06.015

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@article{16438ac030514864b3cd627d997f9197,

title = "Catalytic pyrolysis of polystyrene and polyethylene terephthalate over Al-MSU-F",

abstract = "Catalytic pyrolysis (CP) of waste plastic film over mesoporous catalyst, Al-MSU-F, was investigated using polystyrene (PS) and polyethylene terephthalate (PET) as the model plastic resins. Thermogravimetric analysis of PS and PET indicated that their decomposition temperatures were shifted to the much lower temperature owing to the high diffusion ability of reactant into mesopore of Al-MSU-F. Py-GC/MS analysis for the CP of PS and PET revealed that the large amount of aromatics can be obtained by the use of Al-MSU-F and it was further increased by using the higher catalyst/polymer ratio. CP products of PET over Al-MSU-F showed the high selectivity to mono aromatic hydrocarbons. Meanwhile, those of PS revealed the high selectivity to poly aromatics.",

keywords = "Al-MSU-F, Catalytic pyrolysis, PET, PS, Waste plastic films",

author = "Daejun Oh and Lee, {Hyung Won} and Kim, {Young Min} and Park, {Young Kwon}",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier Ltd. All rights reserved.; 4th International Symposium on Hydrogen Energy, Renewable Energy and Materials, HEREM 2018 ; Conference date: 13-06-2018 Through 14-06-2018",

year = "2018",

doi = "10.1016/j.egypro.2018.06.015",

language = "English",

volume = "144",

pages = "111--117",

journal = "Energy Procedia",

issn = "1876-6102",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Catalytic pyrolysis of polystyrene and polyethylene terephthalate over Al-MSU-F

AU - Oh, Daejun

AU - Lee, Hyung Won

AU - Kim, Young Min

AU - Park, Young Kwon

PY - 2018

Y1 - 2018

N2 - Catalytic pyrolysis (CP) of waste plastic film over mesoporous catalyst, Al-MSU-F, was investigated using polystyrene (PS) and polyethylene terephthalate (PET) as the model plastic resins. Thermogravimetric analysis of PS and PET indicated that their decomposition temperatures were shifted to the much lower temperature owing to the high diffusion ability of reactant into mesopore of Al-MSU-F. Py-GC/MS analysis for the CP of PS and PET revealed that the large amount of aromatics can be obtained by the use of Al-MSU-F and it was further increased by using the higher catalyst/polymer ratio. CP products of PET over Al-MSU-F showed the high selectivity to mono aromatic hydrocarbons. Meanwhile, those of PS revealed the high selectivity to poly aromatics.

AB - Catalytic pyrolysis (CP) of waste plastic film over mesoporous catalyst, Al-MSU-F, was investigated using polystyrene (PS) and polyethylene terephthalate (PET) as the model plastic resins. Thermogravimetric analysis of PS and PET indicated that their decomposition temperatures were shifted to the much lower temperature owing to the high diffusion ability of reactant into mesopore of Al-MSU-F. Py-GC/MS analysis for the CP of PS and PET revealed that the large amount of aromatics can be obtained by the use of Al-MSU-F and it was further increased by using the higher catalyst/polymer ratio. CP products of PET over Al-MSU-F showed the high selectivity to mono aromatic hydrocarbons. Meanwhile, those of PS revealed the high selectivity to poly aromatics.

KW - Al-MSU-F

KW - Catalytic pyrolysis

KW - PET

KW - PS

KW - Waste plastic films

UR - http://www.scopus.com/inward/record.url?scp=85051357112&partnerID=8YFLogxK

U2 - 10.1016/j.egypro.2018.06.015

DO - 10.1016/j.egypro.2018.06.015

M3 - Conference article

AN - SCOPUS:85051357112

SN - 1876-6102

VL - 144

SP - 111

EP - 117

JO - Energy Procedia

JF - Energy Procedia

T2 - 4th International Symposium on Hydrogen Energy, Renewable Energy and Materials, HEREM 2018

Y2 - 13 June 2018 through 14 June 2018

ER -

Catalytic pyrolysis of polystyrene and polyethylene terephthalate over Al-MSU-F

Abstract

Keywords

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