Abstract
The effect of additives such as 1,8-diiodooctane (DIO) and 1-chloronaphthalene (CN) on the electronic structures, charge transport and phase separation of small-molecule-based bulk heterojunction (BHJ) films was investigated. Charge transport properties of the BHJ layers significantly changed via the introduction of additives, even though the molecular energy levels remained unchanged. X-ray photoelectron microscopy (XPM) images show the distribution of each phase of the blend films upon the use of additives. The CN additive, in particular, results in a well-percolated network through the active layer.
Original language | English |
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Pages (from-to) | 4575-4580 |
Number of pages | 6 |
Journal | ACS applied materials & interfaces |
Volume | 5 |
Issue number | 11 |
DOIs | |
State | Published - 12 Jun 2013 |
Keywords
- X-ray photoelectron microscopy
- additive
- bulk heterojunction
- organic field effect transistor
- polarity
- small molecule