TY - JOUR
T1 - Effective use of aluminum-plastic laminate as a feedstock for catalytic pyrolysis over micro and mesoporous catalysts
AU - Siddiqui, Muhammad Zain
AU - Park, Young Kwon
AU - Kang, Yejin
AU - Watanabe, Atsushi
AU - Kim, Seungdo
AU - Kim, Young Min
N1 - Publisher Copyright:
© 2019 Elsevier Ltd
PY - 2019/8/20
Y1 - 2019/8/20
N2 - Thermal and catalytic pyrolysis of aluminum plastic laminate over zeolite catalysts were performed to produce high quality oil. Thermogravimetric analysis of aluminum plastic laminate indicated that the decomposition kinetics of aluminum plastic laminate were changed by interactions between the polymer components during the thermogravimetric analysis of aluminum plastic laminate. The effects of aluminum foil on the aluminum plastic laminate decomposition kinetics were negligible. The catalytic pyrolysis of aluminum plastic laminate over the acid catalysts using tandem-micro reactor-gas chromatography/mass spectrometry produced large amounts of aromatics due to the properties of the main polymers, polyethylene and poly (ethylene terephthalate), in aluminum plastic laminate. Among three catalysts, HZSM-5 (SiO2/Al2O3, 23), HY(30), and Al-MCM-41 (20), HZSM-5 (23) had the highest efficiency on aromatics production followed by HY(30) and Al-MCM-41 (20). Co-feeding aluminum plastic laminate to the catalytic pyrolysis of paper over HZSM-5 (23) and HY(30) was also effective on aromatics production, highlighting the potential use of aluminum plastic laminate to enhance the synergistic aromatics formation during the catalytic pyrolysis of biomass.
AB - Thermal and catalytic pyrolysis of aluminum plastic laminate over zeolite catalysts were performed to produce high quality oil. Thermogravimetric analysis of aluminum plastic laminate indicated that the decomposition kinetics of aluminum plastic laminate were changed by interactions between the polymer components during the thermogravimetric analysis of aluminum plastic laminate. The effects of aluminum foil on the aluminum plastic laminate decomposition kinetics were negligible. The catalytic pyrolysis of aluminum plastic laminate over the acid catalysts using tandem-micro reactor-gas chromatography/mass spectrometry produced large amounts of aromatics due to the properties of the main polymers, polyethylene and poly (ethylene terephthalate), in aluminum plastic laminate. Among three catalysts, HZSM-5 (SiO2/Al2O3, 23), HY(30), and Al-MCM-41 (20), HZSM-5 (23) had the highest efficiency on aromatics production followed by HY(30) and Al-MCM-41 (20). Co-feeding aluminum plastic laminate to the catalytic pyrolysis of paper over HZSM-5 (23) and HY(30) was also effective on aromatics production, highlighting the potential use of aluminum plastic laminate to enhance the synergistic aromatics formation during the catalytic pyrolysis of biomass.
KW - Aluminum-plastic laminates
KW - Aromatic hydrocarbons
KW - Catalytic pyrolysis
KW - HZSM-5
KW - Paper
UR - http://www.scopus.com/inward/record.url?scp=85065817700&partnerID=8YFLogxK
U2 - 10.1016/j.jclepro.2019.04.404
DO - 10.1016/j.jclepro.2019.04.404
M3 - Article
AN - SCOPUS:85065817700
SN - 0959-6526
VL - 229
SP - 1093
EP - 1101
JO - Journal of Cleaner Production
JF - Journal of Cleaner Production
ER -
