Electrical and physicochemical properties of Poly(3,4-ethylenedioxythiophene)-based organic-inorganic hybrid conductive thin films

Jong Seob Choi; Jong Ki Jeon; Young Soo Ko; Young Kwon Park; Sung Gil Kim; Jin Heong Yim

doi:10.1016/j.tsf.2008.11.122

Electrical and physicochemical properties of Poly(3,4-ethylenedioxythiophene)-based organic-inorganic hybrid conductive thin films

Jong Seob Choi, Jong Ki Jeon, Young Soo Ko, Young Kwon Park, Sung Gil Kim, Jin Heong Yim

School of Environmental Engineering

Kongju National University

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

Conductive polymer coating precursors were prepared using poly (3, 4-ehtylenedioxythiophene) (PEDOT) and three kinds of silane precursors (Q type, T type, and bridged T type) through an in-situ organic/inorganic hybrid sol-gel process. The spin-coated precursor films on Poly(ethyleneterephthalate) substrate exhibited fairly good surface resistance (~ 10⁴ Ω/□), transparency (~ 80%) and pencil hardness (2 - 4 H). The solvent resistance of the film using 2, 5-bis (triethoxysilyl)-3, 4-ethylenedioxythiophene (BTES-EDOT) was excellent as compared with the films that used silane precursors due to a high degree of BTES-EDOT crosslinking in the hybrid film. Moreover, EDOT moiety in the BTES-EDOT molecule may contribute to homogeneous dispersion of the PEDOT in the organic-inorganic hybrid film.

Original language	English
Pages (from-to)	3645-3649
Number of pages	5
Journal	Thin Solid Films
Volume	517
Issue number	13
DOIs	https://doi.org/10.1016/j.tsf.2008.11.122
State	Published - 1 May 2009

Keywords

Conductive thin film
Organic-inorganic hybrid
Poly (3, 4-ehtylenedioxythiophene)
Silsesquioxane

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10.1016/j.tsf.2008.11.122

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title = "Electrical and physicochemical properties of Poly(3,4-ethylenedioxythiophene)-based organic-inorganic hybrid conductive thin films",

abstract = "Conductive polymer coating precursors were prepared using poly (3, 4-ehtylenedioxythiophene) (PEDOT) and three kinds of silane precursors (Q type, T type, and bridged T type) through an in-situ organic/inorganic hybrid sol-gel process. The spin-coated precursor films on Poly(ethyleneterephthalate) substrate exhibited fairly good surface resistance (~ 104 Ω/□), transparency (~ 80%) and pencil hardness (2 - 4 H). The solvent resistance of the film using 2, 5-bis (triethoxysilyl)-3, 4-ethylenedioxythiophene (BTES-EDOT) was excellent as compared with the films that used silane precursors due to a high degree of BTES-EDOT crosslinking in the hybrid film. Moreover, EDOT moiety in the BTES-EDOT molecule may contribute to homogeneous dispersion of the PEDOT in the organic-inorganic hybrid film.",

keywords = "Conductive thin film, Organic-inorganic hybrid, Poly (3, 4-ehtylenedioxythiophene), Silsesquioxane",

author = "Choi, {Jong Seob} and Jeon, {Jong Ki} and Ko, {Young Soo} and Park, {Young Kwon} and Kim, {Sung Gil} and Yim, {Jin Heong}",

year = "2009",

month = may,

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doi = "10.1016/j.tsf.2008.11.122",

language = "English",

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T1 - Electrical and physicochemical properties of Poly(3,4-ethylenedioxythiophene)-based organic-inorganic hybrid conductive thin films

AU - Choi, Jong Seob

AU - Jeon, Jong Ki

AU - Ko, Young Soo

AU - Park, Young Kwon

AU - Kim, Sung Gil

AU - Yim, Jin Heong

PY - 2009/5/1

Y1 - 2009/5/1

N2 - Conductive polymer coating precursors were prepared using poly (3, 4-ehtylenedioxythiophene) (PEDOT) and three kinds of silane precursors (Q type, T type, and bridged T type) through an in-situ organic/inorganic hybrid sol-gel process. The spin-coated precursor films on Poly(ethyleneterephthalate) substrate exhibited fairly good surface resistance (~ 104 Ω/□), transparency (~ 80%) and pencil hardness (2 - 4 H). The solvent resistance of the film using 2, 5-bis (triethoxysilyl)-3, 4-ethylenedioxythiophene (BTES-EDOT) was excellent as compared with the films that used silane precursors due to a high degree of BTES-EDOT crosslinking in the hybrid film. Moreover, EDOT moiety in the BTES-EDOT molecule may contribute to homogeneous dispersion of the PEDOT in the organic-inorganic hybrid film.

AB - Conductive polymer coating precursors were prepared using poly (3, 4-ehtylenedioxythiophene) (PEDOT) and three kinds of silane precursors (Q type, T type, and bridged T type) through an in-situ organic/inorganic hybrid sol-gel process. The spin-coated precursor films on Poly(ethyleneterephthalate) substrate exhibited fairly good surface resistance (~ 104 Ω/□), transparency (~ 80%) and pencil hardness (2 - 4 H). The solvent resistance of the film using 2, 5-bis (triethoxysilyl)-3, 4-ethylenedioxythiophene (BTES-EDOT) was excellent as compared with the films that used silane precursors due to a high degree of BTES-EDOT crosslinking in the hybrid film. Moreover, EDOT moiety in the BTES-EDOT molecule may contribute to homogeneous dispersion of the PEDOT in the organic-inorganic hybrid film.

KW - Conductive thin film

KW - Organic-inorganic hybrid

KW - Poly (3, 4-ehtylenedioxythiophene)

KW - Silsesquioxane

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DO - 10.1016/j.tsf.2008.11.122

M3 - Article

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SN - 0040-6090

VL - 517

SP - 3645

EP - 3649

JO - Thin Solid Films

JF - Thin Solid Films

IS - 13

ER -

Electrical and physicochemical properties of Poly(3,4-ethylenedioxythiophene)-based organic-inorganic hybrid conductive thin films

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Keywords

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