Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials

Eun Hwa Lee; Rae su Park; Hannah Kim; Sung Hoon Park; Sang Chul Jung; Jong Ki Jeon; Sang Chai Kim; Young Kwon Park

doi:10.1016/j.jiec.2016.03.019

Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials

Eun Hwa Lee, Rae su Park, Hannah Kim, Sung Hoon Park, Sang Chul Jung, Jong Ki Jeon, Sang Chai Kim, Young Kwon Park

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

131 Scopus citations

Abstract

Hydrodeoxygenation (HDO) of guaiacol in a batch-type reactor at 40 bar and 250 °C was investigated using six different catalysts, Pt/HZSM-5, Pt/Mesoporous Beta, Pt/HBeta, Pt/MMZ_Beta, Pt/Al-MCM-48, and Pt/Si-MCM-48. Among various catalysts, Pt/Mesoporous Beta and Pt/HBeta, which have both large pores and strong acid sites, showed guaiacol conversions larger than 90%. The main product species of HDO of guaiacol was cyclohexane. Meanwhile, Pt/Al-MCM-48 and Pt/MMZ_Beta, which are mesoporous catalysts with weak acid sites, led to lower guaiacol conversions than Pt/Mesoporous Beta and Pt/HBeta and the main product components were cyclohexane and 1,1-bicyclohexyl resulting from CC coupling reactions.

Original language	English
Pages (from-to)	18-21
Number of pages	4
Journal	Journal of Industrial and Engineering Chemistry
Volume	37
DOIs	https://doi.org/10.1016/j.jiec.2016.03.019
State	Published - 25 May 2016

Keywords

Bio-oil
Guaiacol
Hydrodeoxygenation
Mesoporous beta

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@article{8f601fb66ca34e77ba8af897cdcf476a,

title = "Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials",

abstract = "Hydrodeoxygenation (HDO) of guaiacol in a batch-type reactor at 40 bar and 250 °C was investigated using six different catalysts, Pt/HZSM-5, Pt/Mesoporous Beta, Pt/HBeta, Pt/MMZBeta, Pt/Al-MCM-48, and Pt/Si-MCM-48. Among various catalysts, Pt/Mesoporous Beta and Pt/HBeta, which have both large pores and strong acid sites, showed guaiacol conversions larger than 90%. The main product species of HDO of guaiacol was cyclohexane. Meanwhile, Pt/Al-MCM-48 and Pt/MMZBeta, which are mesoporous catalysts with weak acid sites, led to lower guaiacol conversions than Pt/Mesoporous Beta and Pt/HBeta and the main product components were cyclohexane and 1,1-bicyclohexyl resulting from CC coupling reactions.",

keywords = "Bio-oil, Guaiacol, Hydrodeoxygenation, Mesoporous beta",

author = "Lee, {Eun Hwa} and Park, {Rae su} and Hannah Kim and Park, {Sung Hoon} and Jung, {Sang Chul} and Jeon, {Jong Ki} and Kim, {Sang Chai} and Park, {Young Kwon}",

note = "Publisher Copyright: {\textcopyright} 2016 The Korean Society of Industrial and Engineering Chemistry.",

year = "2016",

month = may,

day = "25",

doi = "10.1016/j.jiec.2016.03.019",

language = "English",

volume = "37",

pages = "18--21",

journal = "Journal of Industrial and Engineering Chemistry",

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TY - JOUR

T1 - Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials

AU - Lee, Eun Hwa

AU - Park, Rae su

AU - Kim, Hannah

AU - Park, Sung Hoon

AU - Jung, Sang Chul

AU - Jeon, Jong Ki

AU - Kim, Sang Chai

AU - Park, Young Kwon

PY - 2016/5/25

Y1 - 2016/5/25

N2 - Hydrodeoxygenation (HDO) of guaiacol in a batch-type reactor at 40 bar and 250 °C was investigated using six different catalysts, Pt/HZSM-5, Pt/Mesoporous Beta, Pt/HBeta, Pt/MMZBeta, Pt/Al-MCM-48, and Pt/Si-MCM-48. Among various catalysts, Pt/Mesoporous Beta and Pt/HBeta, which have both large pores and strong acid sites, showed guaiacol conversions larger than 90%. The main product species of HDO of guaiacol was cyclohexane. Meanwhile, Pt/Al-MCM-48 and Pt/MMZBeta, which are mesoporous catalysts with weak acid sites, led to lower guaiacol conversions than Pt/Mesoporous Beta and Pt/HBeta and the main product components were cyclohexane and 1,1-bicyclohexyl resulting from CC coupling reactions.

AB - Hydrodeoxygenation (HDO) of guaiacol in a batch-type reactor at 40 bar and 250 °C was investigated using six different catalysts, Pt/HZSM-5, Pt/Mesoporous Beta, Pt/HBeta, Pt/MMZBeta, Pt/Al-MCM-48, and Pt/Si-MCM-48. Among various catalysts, Pt/Mesoporous Beta and Pt/HBeta, which have both large pores and strong acid sites, showed guaiacol conversions larger than 90%. The main product species of HDO of guaiacol was cyclohexane. Meanwhile, Pt/Al-MCM-48 and Pt/MMZBeta, which are mesoporous catalysts with weak acid sites, led to lower guaiacol conversions than Pt/Mesoporous Beta and Pt/HBeta and the main product components were cyclohexane and 1,1-bicyclohexyl resulting from CC coupling reactions.

KW - Bio-oil

KW - Guaiacol

KW - Hydrodeoxygenation

KW - Mesoporous beta

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U2 - 10.1016/j.jiec.2016.03.019

DO - 10.1016/j.jiec.2016.03.019

M3 - Article

AN - SCOPUS:84978001849

SN - 1226-086X

VL - 37

SP - 18

EP - 21

JO - Journal of Industrial and Engineering Chemistry

JF - Journal of Industrial and Engineering Chemistry

ER -

Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials

Abstract

Keywords

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