Improvement of brightness, color purity, and operational stability of electrochemiluminescence devices with diphenylanthracene derivatives

Heedong Hwang; Jin Kon Kim; Hong Chul Moon

doi:10.1039/c7tc03389c

Improvement of brightness, color purity, and operational stability of electrochemiluminescence devices with diphenylanthracene derivatives

Heedong Hwang, Jin Kon Kim, Hong Chul Moon

Department of Chemical Engineering

Pohang University of Science and Technology

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

We synthesized a highly soluble ionophilic 9,10-diphenylanthracene (I-DPA) by incorporating imidazolium groups into a DPA core. With the prepared I-DPA as an electrochemiluminescence (ECL) luminophore, the resulting ECL device emitted blue light. In comparison with unmodified DPA, a well-known representative ECL blue emitter, the ECL device including I-DPA emitted brighter and purer blue light with improved operational stability. Due to excellent compatibility of the I-DPA with polyvinylacetate (gelator), we could successfully prepare homogeneous ECL gels, and fabricated flexible blue-emitting ECL devices on a plastic substrate.

Original language	English
Pages (from-to)	12513-12519
Number of pages	7
Journal	Journal of Materials Chemistry C
Volume	5
Issue number	47
DOIs	https://doi.org/10.1039/c7tc03389c
State	Published - 2017

Access to Document

10.1039/c7tc03389c

Cite this

@article{d761076628d948fb8aeea0ebff787f7e,

title = "Improvement of brightness, color purity, and operational stability of electrochemiluminescence devices with diphenylanthracene derivatives",

abstract = "We synthesized a highly soluble ionophilic 9,10-diphenylanthracene (I-DPA) by incorporating imidazolium groups into a DPA core. With the prepared I-DPA as an electrochemiluminescence (ECL) luminophore, the resulting ECL device emitted blue light. In comparison with unmodified DPA, a well-known representative ECL blue emitter, the ECL device including I-DPA emitted brighter and purer blue light with improved operational stability. Due to excellent compatibility of the I-DPA with polyvinylacetate (gelator), we could successfully prepare homogeneous ECL gels, and fabricated flexible blue-emitting ECL devices on a plastic substrate.",

author = "Heedong Hwang and Kim, {Jin Kon} and Moon, {Hong Chul}",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

year = "2017",

doi = "10.1039/c7tc03389c",

language = "English",

volume = "5",

pages = "12513--12519",

journal = "Journal of Materials Chemistry C",

issn = "2050-7526",

publisher = "Royal Society of Chemistry",

number = "47",

}

TY - JOUR

T1 - Improvement of brightness, color purity, and operational stability of electrochemiluminescence devices with diphenylanthracene derivatives

AU - Hwang, Heedong

AU - Kim, Jin Kon

AU - Moon, Hong Chul

PY - 2017

Y1 - 2017

N2 - We synthesized a highly soluble ionophilic 9,10-diphenylanthracene (I-DPA) by incorporating imidazolium groups into a DPA core. With the prepared I-DPA as an electrochemiluminescence (ECL) luminophore, the resulting ECL device emitted blue light. In comparison with unmodified DPA, a well-known representative ECL blue emitter, the ECL device including I-DPA emitted brighter and purer blue light with improved operational stability. Due to excellent compatibility of the I-DPA with polyvinylacetate (gelator), we could successfully prepare homogeneous ECL gels, and fabricated flexible blue-emitting ECL devices on a plastic substrate.

AB - We synthesized a highly soluble ionophilic 9,10-diphenylanthracene (I-DPA) by incorporating imidazolium groups into a DPA core. With the prepared I-DPA as an electrochemiluminescence (ECL) luminophore, the resulting ECL device emitted blue light. In comparison with unmodified DPA, a well-known representative ECL blue emitter, the ECL device including I-DPA emitted brighter and purer blue light with improved operational stability. Due to excellent compatibility of the I-DPA with polyvinylacetate (gelator), we could successfully prepare homogeneous ECL gels, and fabricated flexible blue-emitting ECL devices on a plastic substrate.

UR - http://www.scopus.com/inward/record.url?scp=85038209131&partnerID=8YFLogxK

U2 - 10.1039/c7tc03389c

DO - 10.1039/c7tc03389c

M3 - Article

AN - SCOPUS:85038209131

SN - 2050-7526

VL - 5

SP - 12513

EP - 12519

JO - Journal of Materials Chemistry C

JF - Journal of Materials Chemistry C

IS - 47

ER -

Improvement of brightness, color purity, and operational stability of electrochemiluminescence devices with diphenylanthracene derivatives

Abstract

Access to Document

Other files and links

Fingerprint

Cite this