ITO-free inverted polymer solar cells using a GZO cathode modified by ZnO

Soo Ghang Ihn, Kyung Sik Shin, Mi Jin Jin, Xavier Bulliard, Sungyoung Yun, Yeong Suk Choi, Yungi Kim, Jong Hwan Park, Myungsun Sim, Min Kim, Kilwon Cho, Tae Sang Kim, Dukhyun Choi, Jae Young Choi, Woong Choi, Sang Woo Kim

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56 Scopus citations

Abstract

A gallium-doped ZnO (GZO) layer was investigated and compared with a conventional indium-tin-oxide (ITO) layer for use as a cathode in an inverted polymer solar cell based on poly(3-hexylthiophene) (P3HT):[6,6]-phenyl-C 61 butyric acid methyl ester (PCBM) bulk heterojunctions (BHJ). By modifying the GZO cathode with a ZnO thin layer, a high power conversion efficiency (3.4%) comparable to that of an inverted solar cell employing the same P3HT:PCBM BHJ photoactive layer with a conventional ITO/ZnO cathode was achieved. This result indicates that GZO is a transparent electrode material that can potentially be used to replace high-cost ITO.

Original languageEnglish
Pages (from-to)1610-1614
Number of pages5
JournalSolar Energy Materials and Solar Cells
Volume95
Issue number7
DOIs
StatePublished - Jul 2011

Keywords

  • Ga-doped ZnO
  • Inverted polymer solar cell
  • ITO-free
  • Power conversion efficiency
  • Transparent conducting oxide

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