Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity

Jiseul Chun; Sungah Kang; Nojin Park; Eun Ji Park; Xing Jin; Kwang Dae Kim; Hyun Ook Seo; Sang Moon Lee; Hae Jin Kim; Woo Hyun Kwon; Young Kwon Park; Ji Man Kim; Young Dok Kim; Seung Uk Son

doi:10.1021/ja500362w

Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity

Jiseul Chun, Sungah Kang, Nojin Park, Eun Ji Park, Xing Jin, Kwang Dae Kim, Hyun Ook Seo, Sang Moon Lee, Hae Jin Kim, Woo Hyun Kwon, Young Kwon Park, Ji Man Kim, Young Dok Kim, Seung Uk Son

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

207 Scopus citations

Abstract

This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH₂, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH₂ shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.

Original language	English
Pages (from-to)	6786-6789
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	19
DOIs	https://doi.org/10.1021/ja500362w
State	Published - 14 May 2014

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Chun, J., Kang, S., Park, N., Park, E. J., Jin, X., Kim, K. D., Seo, H. O., Lee, S. M., Kim, H. J., Kwon, W. H., Park, Y. K., Kim, J. M., Kim, Y. D., & Son, S. U. (2014). Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity. Journal of the American Chemical Society, 136(19), 6786-6789. https://doi.org/10.1021/ja500362w

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title = "Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity",

abstract = "This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.",

author = "Jiseul Chun and Sungah Kang and Nojin Park and Park, {Eun Ji} and Xing Jin and Kim, {Kwang Dae} and Seo, {Hyun Ook} and Lee, {Sang Moon} and Kim, {Hae Jin} and Kwon, {Woo Hyun} and Park, {Young Kwon} and Kim, {Ji Man} and Kim, {Young Dok} and Son, {Seung Uk}",

year = "2014",

month = may,

day = "14",

doi = "10.1021/ja500362w",

language = "English",

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T1 - Metal-organic framework@microporous organic network

T2 - Hydrophobic adsorbents with a crystalline inner porosity

AU - Chun, Jiseul

AU - Kang, Sungah

AU - Park, Nojin

AU - Park, Eun Ji

AU - Jin, Xing

AU - Kim, Kwang Dae

AU - Seo, Hyun Ook

AU - Lee, Sang Moon

AU - Kim, Hae Jin

AU - Kwon, Woo Hyun

AU - Park, Young Kwon

AU - Kim, Ji Man

AU - Kim, Young Dok

AU - Son, Seung Uk

PY - 2014/5/14

Y1 - 2014/5/14

N2 - This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.

AB - This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.

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U2 - 10.1021/ja500362w

DO - 10.1021/ja500362w

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EP - 6789

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 19

ER -

Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity

Abstract

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