Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity

Jiseul Chun; Sungah Kang; Nojin Park; Eun Ji Park; Xing Jin; Kwang Dae Kim; Hyun Ook Seo; Sang Moon Lee; Hae Jin Kim; Woo Hyun Kwon; Young Kwon Park; Ji Man Kim; Young Dok Kim; Seung Uk Son

doi:10.1021/ja500362w

Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity

Jiseul Chun
, Sungah Kang
, Nojin Park
, Eun Ji Park
, Xing Jin
, Kwang Dae Kim
, Hyun Ook Seo
, Sang Moon Lee
, Hae Jin Kim
, Woo Hyun Kwon
, Young Kwon Park
, Ji Man Kim
, Young Dok Kim
, Seung Uk Son

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

227 Scopus citations

Abstract

This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH₂, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH₂ shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.

Original language	English
Pages (from-to)	6786-6789
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	19
DOIs	https://doi.org/10.1021/ja500362w
State	Published - 14 May 2014

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10.1021/ja500362w

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Chun, J., Kang, S., Park, N., Park, E. J., Jin, X., Kim, K. D., Seo, H. O., Lee, S. M., Kim, H. J., Kwon, W. H., Park, Y. K., Kim, J. M., Kim, Y. D., & Son, S. U. (2014). Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity. Journal of the American Chemical Society, 136(19), 6786-6789. https://doi.org/10.1021/ja500362w

@article{045890d11d3f406c89bff5457e174d09,

title = "Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity",

abstract = "This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.",

author = "Jiseul Chun and Sungah Kang and Nojin Park and Park, \{Eun Ji\} and Xing Jin and Kim, \{Kwang Dae\} and Seo, \{Hyun Ook\} and Lee, \{Sang Moon\} and Kim, \{Hae Jin\} and Kwon, \{Woo Hyun\} and Park, \{Young Kwon\} and Kim, \{Ji Man\} and Kim, \{Young Dok\} and Son, \{Seung Uk\}",

year = "2014",

month = may,

day = "14",

doi = "10.1021/ja500362w",

language = "English",

volume = "136",

pages = "6786--6789",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Metal-organic framework@microporous organic network

T2 - Hydrophobic adsorbents with a crystalline inner porosity

AU - Chun, Jiseul

AU - Kang, Sungah

AU - Park, Nojin

AU - Park, Eun Ji

AU - Jin, Xing

AU - Kim, Kwang Dae

AU - Seo, Hyun Ook

AU - Lee, Sang Moon

AU - Kim, Hae Jin

AU - Kwon, Woo Hyun

AU - Park, Young Kwon

AU - Kim, Ji Man

AU - Kim, Young Dok

AU - Son, Seung Uk

PY - 2014/5/14

Y1 - 2014/5/14

N2 - This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.

AB - This work reports the synthesis and application of metal-organic framework (MOF)@microporous organic network (MON) hybrid materials. Coating a MOF, UiO-66-NH2, with MONs forms hybrid microporous materials with hydrophobic surfaces. The original UiO-66-NH2 shows good wettability in water. In comparison, the MOF@MON hybrid materials float on water and show excellent performance for adsorption of a model organic compound, toluene, in water. Chemical etching of the MOF results in the formation of hollow MON materials.

UR - https://www.scopus.com/pages/publications/84900801380

U2 - 10.1021/ja500362w

DO - 10.1021/ja500362w

M3 - Article

AN - SCOPUS:84900801380

SN - 0002-7863

VL - 136

SP - 6786

EP - 6789

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 19

ER -

Metal-organic framework@microporous organic network: Hydrophobic adsorbents with a crystalline inner porosity

Abstract

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