Modified combinatorial factor in the hole theory

Mooho Hong; Jaeeon Chang; Hwayong Kim; Jiho Park

doi:10.1016/S0378-3812(99)00191-0

Modified combinatorial factor in the hole theory

Mooho Hong, Jaeeon Chang, Hwayong Kim, Jiho Park

Department of Chemical Engineering

Research output: Contribution to journal › Conference article › peer-review

1 Scopus citations

Abstract

To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and free volume expression, a new equation of state is derived, and is used to calculate the PVT behaviors of 10 pure low molecular weight liquid systems. In addition, the PVT behavior of carbontetrachloride/cyclohexane binary system is calculated. Good agreements between the theory and experimental data are obtained.

Original language	English
Pages (from-to)	271-281
Number of pages	11
Journal	Fluid Phase Equilibria
Volume	161
Issue number	2
DOIs	https://doi.org/10.1016/S0378-3812(99)00191-0
State	Published - 24 Jul 1999
Event	Proceedings of the 1998 5th Asian Thermophysical Properties Conference - Seoul, S Kor Duration: 3 Aug 1998 → 2 Sep 1998

Keywords

Combinatorial factor
Equation of state
Liquid state
Mixture
PVT

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10.1016/S0378-3812(99)00191-0

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title = "Modified combinatorial factor in the hole theory",

abstract = "To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and free volume expression, a new equation of state is derived, and is used to calculate the PVT behaviors of 10 pure low molecular weight liquid systems. In addition, the PVT behavior of carbontetrachloride/cyclohexane binary system is calculated. Good agreements between the theory and experimental data are obtained.",

keywords = "Combinatorial factor, Equation of state, Liquid state, Mixture, PVT",

author = "Mooho Hong and Jaeeon Chang and Hwayong Kim and Jiho Park",

year = "1999",

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doi = "10.1016/S0378-3812(99)00191-0",

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journal = "Fluid Phase Equilibria",

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number = "2",

note = "Proceedings of the 1998 5th Asian Thermophysical Properties Conference ; Conference date: 03-08-1998 Through 02-09-1998",

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TY - JOUR

T1 - Modified combinatorial factor in the hole theory

AU - Hong, Mooho

AU - Chang, Jaeeon

AU - Kim, Hwayong

AU - Park, Jiho

PY - 1999/7/24

Y1 - 1999/7/24

N2 - To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and free volume expression, a new equation of state is derived, and is used to calculate the PVT behaviors of 10 pure low molecular weight liquid systems. In addition, the PVT behavior of carbontetrachloride/cyclohexane binary system is calculated. Good agreements between the theory and experimental data are obtained.

AB - To describe the behavior of liquid state by hole theory, Flory's combinatorial factor used in the partition function of the hole theory is modified in a general form by assuming that unit segment of chain molecule can occupy more than one unit cell or lattice. From this combinatorial factor and free volume expression, a new equation of state is derived, and is used to calculate the PVT behaviors of 10 pure low molecular weight liquid systems. In addition, the PVT behavior of carbontetrachloride/cyclohexane binary system is calculated. Good agreements between the theory and experimental data are obtained.

KW - Combinatorial factor

KW - Equation of state

KW - Liquid state

KW - Mixture

KW - PVT

UR - https://www.scopus.com/pages/publications/0033600303

U2 - 10.1016/S0378-3812(99)00191-0

DO - 10.1016/S0378-3812(99)00191-0

M3 - Conference article

AN - SCOPUS:0033600303

SN - 0378-3812

VL - 161

SP - 271

EP - 281

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

IS - 2

T2 - Proceedings of the 1998 5th Asian Thermophysical Properties Conference

Y2 - 3 August 1998 through 2 September 1998

ER -

Modified combinatorial factor in the hole theory

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Keywords

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