N-[2-(N′-hydroxy-N-oxidodiaziniumyl)-3-methylbutyl]octanamide

Rakwoo Chang; Whanchul Shin

doi:10.1107/S0108270198000729

N-[2-(N′-hydroxy-N-oxidodiaziniumyl)-3-methylbutyl]octanamide

Rakwoo Chang, Whanchul Shin

Department of Applied Chemistry

Seoul National University

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

The title compound, C₁₃H₂₇N₃O₃, exists in the N′-hydroxy-N-oxidodiaziniumyl [R-N(O)=N-OH] form instead of the tautomeric N-hydroxy-N′-nitrosoamino [R-N(OH)-N=O] form. Variation of the bond distances and good planarity indicate that resonance takes place in the [N₂O₂]H moiety. The molecule assumes an overall elongated conformation. Two centro-symmetrically-related molecules form a dimer via two three-centered N1-H⋯O2/O3 hydrogen bonds. Crystal packing consists of alternating hydrophilic and hydrophobic layers.

Original language	English
Pages (from-to)	827-829
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	6
DOIs	https://doi.org/10.1107/S0108270198000729
State	Published - 15 Jun 1998

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title = "N-[2-(N′-hydroxy-N-oxidodiaziniumyl)-3-methylbutyl]octanamide",

abstract = "The title compound, C13H27N3O3, exists in the N′-hydroxy-N-oxidodiaziniumyl [R-N(O)=N-OH] form instead of the tautomeric N-hydroxy-N′-nitrosoamino [R-N(OH)-N=O] form. Variation of the bond distances and good planarity indicate that resonance takes place in the [N2O2]H moiety. The molecule assumes an overall elongated conformation. Two centro-symmetrically-related molecules form a dimer via two three-centered N1-H⋯O2/O3 hydrogen bonds. Crystal packing consists of alternating hydrophilic and hydrophobic layers.",

author = "Rakwoo Chang and Whanchul Shin",

year = "1998",

month = jun,

day = "15",

doi = "10.1107/S0108270198000729",

language = "English",

volume = "54",

pages = "827--829",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "John Wiley \& Sons Inc.",

number = "6",

}

TY - JOUR

T1 - N-[2-(N′-hydroxy-N-oxidodiaziniumyl)-3-methylbutyl]octanamide

AU - Chang, Rakwoo

AU - Shin, Whanchul

PY - 1998/6/15

Y1 - 1998/6/15

N2 - The title compound, C13H27N3O3, exists in the N′-hydroxy-N-oxidodiaziniumyl [R-N(O)=N-OH] form instead of the tautomeric N-hydroxy-N′-nitrosoamino [R-N(OH)-N=O] form. Variation of the bond distances and good planarity indicate that resonance takes place in the [N2O2]H moiety. The molecule assumes an overall elongated conformation. Two centro-symmetrically-related molecules form a dimer via two three-centered N1-H⋯O2/O3 hydrogen bonds. Crystal packing consists of alternating hydrophilic and hydrophobic layers.

AB - The title compound, C13H27N3O3, exists in the N′-hydroxy-N-oxidodiaziniumyl [R-N(O)=N-OH] form instead of the tautomeric N-hydroxy-N′-nitrosoamino [R-N(OH)-N=O] form. Variation of the bond distances and good planarity indicate that resonance takes place in the [N2O2]H moiety. The molecule assumes an overall elongated conformation. Two centro-symmetrically-related molecules form a dimer via two three-centered N1-H⋯O2/O3 hydrogen bonds. Crystal packing consists of alternating hydrophilic and hydrophobic layers.

UR - https://www.scopus.com/pages/publications/4243603284

U2 - 10.1107/S0108270198000729

DO - 10.1107/S0108270198000729

M3 - Article

AN - SCOPUS:4243603284

SN - 0108-2701

VL - 54

SP - 827

EP - 829

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 6

ER -

N-[2-(N′-hydroxy-N-oxidodiaziniumyl)-3-methylbutyl]octanamide

Abstract

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