Oligomerization and isomerization of dicyclopentadiene over mesoporous materials produced from zeolite beta

Jinhan Kim; Jeongsik Han; Tae Soo Kwon; Young Kwon Park; Jong Ki Jeon

doi:10.1016/j.cattod.2014.02.004

Oligomerization and isomerization of dicyclopentadiene over mesoporous materials produced from zeolite beta

Jinhan Kim, Jeongsik Han, Tae Soo Kwon, Young Kwon Park, Jong Ki Jeon

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

Mesoporous materials synthesized from commercial zeolite beta were applied to a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction. A highly ordered mesoporous aluminosolicate, MMZ-Hβ was synthesized using commercially available zeolite beta as its framework source. It was confirmed that MMZ-Hβ has smaller surface area and pore volume than zeolite beta but mesopores were well developed. Though the amount and the strength of acid sites over MMZ-Hβ decreased compared with zeolite beta, the MMZ-Hβ catalyst shows high reaction activity and selectivity in a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction, which can be attributed to the large pore size of MMZ-Hβ which is favorable for the diffusion of reactant, intermediate, and product.

Original language	English
Pages (from-to)	69-74
Number of pages	6
Journal	Catalysis Today
Volume	232
DOIs	https://doi.org/10.1016/j.cattod.2014.02.004
State	Published - 1 Sep 2014

Keywords

Dicyclopentadiene oligomerization
Mesoporous aluminosolicate
Tricyclopentadiene isomer
Zeolite beta

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10.1016/j.cattod.2014.02.004

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title = "Oligomerization and isomerization of dicyclopentadiene over mesoporous materials produced from zeolite beta",

abstract = "Mesoporous materials synthesized from commercial zeolite beta were applied to a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction. A highly ordered mesoporous aluminosolicate, MMZ-Hβ was synthesized using commercially available zeolite beta as its framework source. It was confirmed that MMZ-Hβ has smaller surface area and pore volume than zeolite beta but mesopores were well developed. Though the amount and the strength of acid sites over MMZ-Hβ decreased compared with zeolite beta, the MMZ-Hβ catalyst shows high reaction activity and selectivity in a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction, which can be attributed to the large pore size of MMZ-Hβ which is favorable for the diffusion of reactant, intermediate, and product.",

keywords = "Dicyclopentadiene oligomerization, Mesoporous aluminosolicate, Tricyclopentadiene isomer, Zeolite beta",

author = "Jinhan Kim and Jeongsik Han and Kwon, {Tae Soo} and Park, {Young Kwon} and Jeon, {Jong Ki}",

year = "2014",

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doi = "10.1016/j.cattod.2014.02.004",

language = "English",

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pages = "69--74",

journal = "Catalysis Today",

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T1 - Oligomerization and isomerization of dicyclopentadiene over mesoporous materials produced from zeolite beta

AU - Kim, Jinhan

AU - Han, Jeongsik

AU - Kwon, Tae Soo

AU - Park, Young Kwon

AU - Jeon, Jong Ki

PY - 2014/9/1

Y1 - 2014/9/1

N2 - Mesoporous materials synthesized from commercial zeolite beta were applied to a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction. A highly ordered mesoporous aluminosolicate, MMZ-Hβ was synthesized using commercially available zeolite beta as its framework source. It was confirmed that MMZ-Hβ has smaller surface area and pore volume than zeolite beta but mesopores were well developed. Though the amount and the strength of acid sites over MMZ-Hβ decreased compared with zeolite beta, the MMZ-Hβ catalyst shows high reaction activity and selectivity in a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction, which can be attributed to the large pore size of MMZ-Hβ which is favorable for the diffusion of reactant, intermediate, and product.

AB - Mesoporous materials synthesized from commercial zeolite beta were applied to a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction. A highly ordered mesoporous aluminosolicate, MMZ-Hβ was synthesized using commercially available zeolite beta as its framework source. It was confirmed that MMZ-Hβ has smaller surface area and pore volume than zeolite beta but mesopores were well developed. Though the amount and the strength of acid sites over MMZ-Hβ decreased compared with zeolite beta, the MMZ-Hβ catalyst shows high reaction activity and selectivity in a dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization reaction, which can be attributed to the large pore size of MMZ-Hβ which is favorable for the diffusion of reactant, intermediate, and product.

KW - Dicyclopentadiene oligomerization

KW - Mesoporous aluminosolicate

KW - Tricyclopentadiene isomer

KW - Zeolite beta

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U2 - 10.1016/j.cattod.2014.02.004

DO - 10.1016/j.cattod.2014.02.004

M3 - Article

AN - SCOPUS:84901061417

SN - 0920-5861

VL - 232

SP - 69

EP - 74

JO - Catalysis Today

JF - Catalysis Today

ER -

Oligomerization and isomerization of dicyclopentadiene over mesoporous materials produced from zeolite beta

Abstract

Keywords

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