Performance of platinum doping on spent alkaline battery-based catalyst for complete oxidation of o-xylene

Young Kwon Park, Sang Chul Jung, Ho Young Jung, Shin Ying Foong, Su Shiung Lam, Sang Chai Kim

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

Oxidation of o-xylene was performed using alkaline battery-based catalyst doped with platinum to investigate the properties and activities. O-xylene was selected as the model of volatile organic compound (VOC) in this work. Physicochemical properties of the selected catalysts were characterized by FE/TEM (field emission transmission electron microscopy), BET (Brunauer-Emmett-Teller) analysis, XRD (X-ray powder diffraction), SEM/EDX (scanning electron microscopy/energy dispersive X-ray spectroscopy), and H2-TPR (hydrogen temperature programmed reduction). Major elements of the spent alkaline battery-based catalyst treated with sulfuric acid solution [SAB (400) catalyst] were manganese, zinc, iron, oxygen, carbon, chlorine, aluminum, sodium, silicon, and potassium. Increasing the doping amount of platinum on SAB (400) catalyst from 0.1 to 1 wt% increased particle size of platinum and lowered the temperature of TPR (TTP) for SAB (400) catalyst. Better redox properties were achieved with an increase in the o-xylene conversion according to the doping amount of platinum. When GHSV (gas hourly space velocity) was 40,000 h−1, o-xylene was oxidized completely over SAB (400) catalyst and 1.0 wt% Pt/SAB(400) catalyst at temperatures of 400 °C and 280 °C, respectively.

Original languageEnglish
Pages (from-to)24552-24557
Number of pages6
JournalEnvironmental Science and Pollution Research
Volume28
Issue number19
DOIs
StatePublished - May 2021

Keywords

  • Acid treatment
  • Complete oxidation
  • O-xylene
  • Platinum
  • Spent alkaline battery

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