Preparation of Alkylated and Perfluorinated ZnPc-modified Carbon Nanotubes and their Application as Conductive Fillers for Poly(vinylidene fluoride) Composite Dielectrics

Sun Mi Hong; Anil Kumar Mutyala; Myung Joo Cha; Jung Hwa Seo; Young Ah Kang; Jong S. Park

doi:10.1002/bkcs.11246

Preparation of Alkylated and Perfluorinated ZnPc-modified Carbon Nanotubes and their Application as Conductive Fillers for Poly(vinylidene fluoride) Composite Dielectrics

Sun Mi Hong, Anil Kumar Mutyala, Myung Joo Cha, Jung Hwa Seo, Young Ah Kang, Jong S. Park

Department of Physics

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

This study includes the synthesis and application of unsymmetrical zinc phthalocyanines (ZnPcs) 1 and 2 with three tertiary-butylated (tBu) and hexyl-tridecafluoro (C₆F₁₃) groups that are further connected with carbon nanotubes (CNTs) through an amide bonding to yield Pc-functionalized CNTs 3 and 4, respectively. The properties of the resulting Pc-CNT complexes are thoroughly investigated using various analytical techniques, revealing that 3 and 4 enhanced the dispersion and adhesion properties of the CNTs to poly(vinylidene fluoride) (PVDF) matrix, and thereby improved the electrical and dielectric properties. Particularly, the presence of long and fluorinated substituents in 4 allowed for better interfacial compatibility compared to alkylated Pc-CNT 3, leading to more stable dielectric behaviors. Our work has demonstrated that perfluorinated and alkylated Pc-CNT complex could be facile and effective approach toward high-performance polymer-based dielectrics.

Original language	English
Pages (from-to)	1190-1195
Number of pages	6
Journal	Bulletin of the Korean Chemical Society
Volume	38
Issue number	10
DOIs	https://doi.org/10.1002/bkcs.11246
State	Published - Oct 2017

Keywords

Alkylated or perfluorinated substituents
Dielectric polymer film
Dielectric property
Polymer-based composites
Substituted zinc-phthalocyanine

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10.1002/bkcs.11246

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@article{e304790096c448da9d986829a566b710,

title = "Preparation of Alkylated and Perfluorinated ZnPc-modified Carbon Nanotubes and their Application as Conductive Fillers for Poly(vinylidene fluoride) Composite Dielectrics",

abstract = "This study includes the synthesis and application of unsymmetrical zinc phthalocyanines (ZnPcs) 1 and 2 with three tertiary-butylated (tBu) and hexyl-tridecafluoro (C6F13) groups that are further connected with carbon nanotubes (CNTs) through an amide bonding to yield Pc-functionalized CNTs 3 and 4, respectively. The properties of the resulting Pc-CNT complexes are thoroughly investigated using various analytical techniques, revealing that 3 and 4 enhanced the dispersion and adhesion properties of the CNTs to poly(vinylidene fluoride) (PVDF) matrix, and thereby improved the electrical and dielectric properties. Particularly, the presence of long and fluorinated substituents in 4 allowed for better interfacial compatibility compared to alkylated Pc-CNT 3, leading to more stable dielectric behaviors. Our work has demonstrated that perfluorinated and alkylated Pc-CNT complex could be facile and effective approach toward high-performance polymer-based dielectrics.",

keywords = "Alkylated or perfluorinated substituents, Dielectric polymer film, Dielectric property, Polymer-based composites, Substituted zinc-phthalocyanine",

author = "Hong, {Sun Mi} and Mutyala, {Anil Kumar} and Cha, {Myung Joo} and Seo, {Jung Hwa} and Kang, {Young Ah} and Park, {Jong S.}",

note = "Publisher Copyright: {\textcopyright} 2017 Korean Chemical Society, Seoul & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",

year = "2017",

month = oct,

doi = "10.1002/bkcs.11246",

language = "English",

volume = "38",

pages = "1190--1195",

journal = "Bulletin of the Korean Chemical Society",

issn = "0253-2964",

publisher = "Wiley-Blackwell",

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}

Preparation of Alkylated and Perfluorinated ZnPc-modified Carbon Nanotubes and their Application as Conductive Fillers for Poly(vinylidene fluoride) Composite Dielectrics. / Hong, Sun Mi; Mutyala, Anil Kumar; Cha, Myung Joo et al.
In: Bulletin of the Korean Chemical Society, Vol. 38, No. 10, 10.2017, p. 1190-1195.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Preparation of Alkylated and Perfluorinated ZnPc-modified Carbon Nanotubes and their Application as Conductive Fillers for Poly(vinylidene fluoride) Composite Dielectrics

AU - Hong, Sun Mi

AU - Mutyala, Anil Kumar

AU - Cha, Myung Joo

AU - Seo, Jung Hwa

AU - Kang, Young Ah

AU - Park, Jong S.

PY - 2017/10

Y1 - 2017/10

N2 - This study includes the synthesis and application of unsymmetrical zinc phthalocyanines (ZnPcs) 1 and 2 with three tertiary-butylated (tBu) and hexyl-tridecafluoro (C6F13) groups that are further connected with carbon nanotubes (CNTs) through an amide bonding to yield Pc-functionalized CNTs 3 and 4, respectively. The properties of the resulting Pc-CNT complexes are thoroughly investigated using various analytical techniques, revealing that 3 and 4 enhanced the dispersion and adhesion properties of the CNTs to poly(vinylidene fluoride) (PVDF) matrix, and thereby improved the electrical and dielectric properties. Particularly, the presence of long and fluorinated substituents in 4 allowed for better interfacial compatibility compared to alkylated Pc-CNT 3, leading to more stable dielectric behaviors. Our work has demonstrated that perfluorinated and alkylated Pc-CNT complex could be facile and effective approach toward high-performance polymer-based dielectrics.

AB - This study includes the synthesis and application of unsymmetrical zinc phthalocyanines (ZnPcs) 1 and 2 with three tertiary-butylated (tBu) and hexyl-tridecafluoro (C6F13) groups that are further connected with carbon nanotubes (CNTs) through an amide bonding to yield Pc-functionalized CNTs 3 and 4, respectively. The properties of the resulting Pc-CNT complexes are thoroughly investigated using various analytical techniques, revealing that 3 and 4 enhanced the dispersion and adhesion properties of the CNTs to poly(vinylidene fluoride) (PVDF) matrix, and thereby improved the electrical and dielectric properties. Particularly, the presence of long and fluorinated substituents in 4 allowed for better interfacial compatibility compared to alkylated Pc-CNT 3, leading to more stable dielectric behaviors. Our work has demonstrated that perfluorinated and alkylated Pc-CNT complex could be facile and effective approach toward high-performance polymer-based dielectrics.

KW - Alkylated or perfluorinated substituents

KW - Dielectric polymer film

KW - Dielectric property

KW - Polymer-based composites

KW - Substituted zinc-phthalocyanine

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Preparation of Alkylated and Perfluorinated ZnPc-modified Carbon Nanotubes and their Application as Conductive Fillers for Poly(vinylidene fluoride) Composite Dielectrics

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