Pyrolysis of polypropylene over mesoporous MCM-48 material

Hyun Ju Park; Jin Heong Yim; Jong Ki Jeon; Ji Man Kim; Kyung Seun Yoo; Young Kwon Park

doi:10.1016/j.jpcs.2007.10.083

Pyrolysis of polypropylene over mesoporous MCM-48 material

Hyun Ju Park
, Jin Heong Yim
, Jong Ki Jeon
, Ji Man Kim
, Kyung Seun Yoo
, Young Kwon Park

School of Environmental Engineering

University of Seoul
Kongju National University
Sungkyunkwan University
Kwangwoon University

Research output: Contribution to journal › Article › peer-review

41 Scopus citations

Abstract

The catalytic performance of mesoporous MCM-48 materials in the degradation of polypropylene (PP) was evaluated using a thermogravimetric analyzer and batch reactor. The activation energy of PP degradation was significantly lowered by the addition of Al-MCM-48. The catalytic conversion was also higher over Al-MCM-48 than over Si-MCM-48. Al-MCM-48 mainly generated C₇-C₁₀ hydrocarbons, while Si-MCM-48 exhibited a relatively broader distribution of oil products (C₇-C₁₄). Al-MCM-48 showed high catalytic stability for the PP degradation.

Original language	English
Pages (from-to)	1125-1128
Number of pages	4
Journal	Journal of Physics and Chemistry of Solids
Volume	69
Issue number	5-6
DOIs	https://doi.org/10.1016/j.jpcs.2007.10.083
State	Published - May 2008

Keywords

A. Polymers
C. Thermogravimetric analysis

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10.1016/j.jpcs.2007.10.083

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title = "Pyrolysis of polypropylene over mesoporous MCM-48 material",

abstract = "The catalytic performance of mesoporous MCM-48 materials in the degradation of polypropylene (PP) was evaluated using a thermogravimetric analyzer and batch reactor. The activation energy of PP degradation was significantly lowered by the addition of Al-MCM-48. The catalytic conversion was also higher over Al-MCM-48 than over Si-MCM-48. Al-MCM-48 mainly generated C7-C10 hydrocarbons, while Si-MCM-48 exhibited a relatively broader distribution of oil products (C7-C14). Al-MCM-48 showed high catalytic stability for the PP degradation.",

keywords = "A. Polymers, C. Thermogravimetric analysis",

author = "\{Ju Park\}, Hyun and Yim, \{Jin Heong\} and Jeon, \{Jong Ki\} and \{Man Kim\}, Ji and Yoo, \{Kyung Seun\} and Park, \{Young Kwon\}",

year = "2008",

month = may,

doi = "10.1016/j.jpcs.2007.10.083",

language = "English",

volume = "69",

pages = "1125--1128",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier Ltd.",

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TY - JOUR

T1 - Pyrolysis of polypropylene over mesoporous MCM-48 material

AU - Ju Park, Hyun

AU - Yim, Jin Heong

AU - Jeon, Jong Ki

AU - Man Kim, Ji

AU - Yoo, Kyung Seun

AU - Park, Young Kwon

PY - 2008/5

Y1 - 2008/5

N2 - The catalytic performance of mesoporous MCM-48 materials in the degradation of polypropylene (PP) was evaluated using a thermogravimetric analyzer and batch reactor. The activation energy of PP degradation was significantly lowered by the addition of Al-MCM-48. The catalytic conversion was also higher over Al-MCM-48 than over Si-MCM-48. Al-MCM-48 mainly generated C7-C10 hydrocarbons, while Si-MCM-48 exhibited a relatively broader distribution of oil products (C7-C14). Al-MCM-48 showed high catalytic stability for the PP degradation.

AB - The catalytic performance of mesoporous MCM-48 materials in the degradation of polypropylene (PP) was evaluated using a thermogravimetric analyzer and batch reactor. The activation energy of PP degradation was significantly lowered by the addition of Al-MCM-48. The catalytic conversion was also higher over Al-MCM-48 than over Si-MCM-48. Al-MCM-48 mainly generated C7-C10 hydrocarbons, while Si-MCM-48 exhibited a relatively broader distribution of oil products (C7-C14). Al-MCM-48 showed high catalytic stability for the PP degradation.

KW - A. Polymers

KW - C. Thermogravimetric analysis

UR - https://www.scopus.com/pages/publications/43449120955

U2 - 10.1016/j.jpcs.2007.10.083

DO - 10.1016/j.jpcs.2007.10.083

M3 - Article

AN - SCOPUS:43449120955

SN - 0022-3697

VL - 69

SP - 1125

EP - 1128

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

IS - 5-6

ER -

Pyrolysis of polypropylene over mesoporous MCM-48 material

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Keywords

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