Rhodium complexes immobilized on nanoporous silica for octene hydroformylation

So Young Yun; Min Jun Seong; Jin Heong Yim; Young Soo Ko; Young Kwon Park; Jong Ki Jeon

Rhodium complexes immobilized on nanoporous silica for octene hydroformylation

So Young Yun, Min Jun Seong, Jin Heong Yim, Young Soo Ko, Young Kwon Park, Jong Ki Jeon

School of Environmental Engineering

Kongju National University

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Rhodium was immobilized on the aminated SBA-15 in order to evaluate it as a heterogeneous catalyst for 1-octene hydroformylation. The triphenylphosphine ligand remarkably improved the activity. Hydroformylation activity of 1-octene was higher than that of branched and/or inner octenes. At a reaction temperature of 120°C, hydroformylation of 1-octene was more prevailing than isomerization, and thus the nonyl aldehyde yield reached a maximum.

Original language	English
Pages (from-to)	154-157
Number of pages	4
Journal	Reviews on Advanced Materials Science
Volume	28
Issue number	2
State	Published - Jul 2011

Cite this

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abstract = "Rhodium was immobilized on the aminated SBA-15 in order to evaluate it as a heterogeneous catalyst for 1-octene hydroformylation. The triphenylphosphine ligand remarkably improved the activity. Hydroformylation activity of 1-octene was higher than that of branched and/or inner octenes. At a reaction temperature of 120°C, hydroformylation of 1-octene was more prevailing than isomerization, and thus the nonyl aldehyde yield reached a maximum.",

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T1 - Rhodium complexes immobilized on nanoporous silica for octene hydroformylation

AU - Yun, So Young

AU - Seong, Min Jun

AU - Yim, Jin Heong

AU - Ko, Young Soo

AU - Park, Young Kwon

AU - Jeon, Jong Ki

PY - 2011/7

Y1 - 2011/7

N2 - Rhodium was immobilized on the aminated SBA-15 in order to evaluate it as a heterogeneous catalyst for 1-octene hydroformylation. The triphenylphosphine ligand remarkably improved the activity. Hydroformylation activity of 1-octene was higher than that of branched and/or inner octenes. At a reaction temperature of 120°C, hydroformylation of 1-octene was more prevailing than isomerization, and thus the nonyl aldehyde yield reached a maximum.

AB - Rhodium was immobilized on the aminated SBA-15 in order to evaluate it as a heterogeneous catalyst for 1-octene hydroformylation. The triphenylphosphine ligand remarkably improved the activity. Hydroformylation activity of 1-octene was higher than that of branched and/or inner octenes. At a reaction temperature of 120°C, hydroformylation of 1-octene was more prevailing than isomerization, and thus the nonyl aldehyde yield reached a maximum.

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M3 - Article

AN - SCOPUS:79959773855

SN - 1606-5131

VL - 28

SP - 154

EP - 157

JO - Reviews on Advanced Materials Science

JF - Reviews on Advanced Materials Science

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ER -

Rhodium complexes immobilized on nanoporous silica for octene hydroformylation

Abstract

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