Solution-Processable Organic Photovoltaic Cell Based on the Oligothiophene with Solubilizing β-alkyl Groups

Eunhee Lim

doi:10.1080/15421406.2014.944786

Solution-Processable Organic Photovoltaic Cell Based on the Oligothiophene with Solubilizing β-alkyl Groups

Eunhee Lim

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We synthesized a linear π-conjugated small molecule (β-DH5T) based on thiophene, using the palladium-catalyzed Suzuki coupling. The oligothiophene was designed to contain β-substituted solubilizing alkyl groups to facilitate solution processing. The organic photovoltaic cell based on β-DH5T:PC71BM gave a power conversion efficiency of 0.46% with a short-circuit current of 4.69 mA/cm², an open-circuit voltage of 0.60 V, and a fill factor of 0.35, giving under AM 1.5G illumination (100 mW/cm²). The optical and electrochemical properties and molecular alignment of oligothiophene were investigated using UV-visible absorption spectroscopy, cyclic voltammetry, and thin-film X-ray diffraction studies.

Original language	English
Pages (from-to)	251-257
Number of pages	7
Journal	Molecular Crystals and Liquid Crystals
Volume	602
Issue number	1
DOIs	https://doi.org/10.1080/15421406.2014.944786
State	Published - 13 Oct 2014

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Organic photovoltaic cells
oligothiophene
small molecule
solar cells
solution-processing

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10.1080/15421406.2014.944786

Cite this

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title = "Solution-Processable Organic Photovoltaic Cell Based on the Oligothiophene with Solubilizing β-alkyl Groups",

abstract = "We synthesized a linear π-conjugated small molecule (β-DH5T) based on thiophene, using the palladium-catalyzed Suzuki coupling. The oligothiophene was designed to contain β-substituted solubilizing alkyl groups to facilitate solution processing. The organic photovoltaic cell based on β-DH5T:PC71BM gave a power conversion efficiency of 0.46\% with a short-circuit current of 4.69 mA/cm2, an open-circuit voltage of 0.60 V, and a fill factor of 0.35, giving under AM 1.5G illumination (100 mW/cm2). The optical and electrochemical properties and molecular alignment of oligothiophene were investigated using UV-visible absorption spectroscopy, cyclic voltammetry, and thin-film X-ray diffraction studies.",

keywords = "Organic photovoltaic cells, oligothiophene, small molecule, solar cells, solution-processing",

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T1 - Solution-Processable Organic Photovoltaic Cell Based on the Oligothiophene with Solubilizing β-alkyl Groups

AU - Lim, Eunhee

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N2 - We synthesized a linear π-conjugated small molecule (β-DH5T) based on thiophene, using the palladium-catalyzed Suzuki coupling. The oligothiophene was designed to contain β-substituted solubilizing alkyl groups to facilitate solution processing. The organic photovoltaic cell based on β-DH5T:PC71BM gave a power conversion efficiency of 0.46% with a short-circuit current of 4.69 mA/cm2, an open-circuit voltage of 0.60 V, and a fill factor of 0.35, giving under AM 1.5G illumination (100 mW/cm2). The optical and electrochemical properties and molecular alignment of oligothiophene were investigated using UV-visible absorption spectroscopy, cyclic voltammetry, and thin-film X-ray diffraction studies.

AB - We synthesized a linear π-conjugated small molecule (β-DH5T) based on thiophene, using the palladium-catalyzed Suzuki coupling. The oligothiophene was designed to contain β-substituted solubilizing alkyl groups to facilitate solution processing. The organic photovoltaic cell based on β-DH5T:PC71BM gave a power conversion efficiency of 0.46% with a short-circuit current of 4.69 mA/cm2, an open-circuit voltage of 0.60 V, and a fill factor of 0.35, giving under AM 1.5G illumination (100 mW/cm2). The optical and electrochemical properties and molecular alignment of oligothiophene were investigated using UV-visible absorption spectroscopy, cyclic voltammetry, and thin-film X-ray diffraction studies.

KW - Organic photovoltaic cells

KW - oligothiophene

KW - small molecule

KW - solar cells

KW - solution-processing

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DO - 10.1080/15421406.2014.944786

M3 - Article

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SN - 1542-1406

VL - 602

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JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Solution-Processable Organic Photovoltaic Cell Based on the Oligothiophene with Solubilizing β-alkyl Groups

Abstract

UN SDGs

Keywords

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