Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides

Erik Schwartz; Eunhee Lim; Chandrakala M. Gowda; Andrea Liscio; Oliver Fenwick; Guoli Tu; Vincenzo Palermo; Rene De Gelder; Jeroen J.L.M. Cornelissen; Ernst R.H. Van Eck; Arno P.M. Kentgens; Franco Cacialli; Roeland J.M. Nolte; Paolo Samorì; Wilhelm T.S. Huck; Alan E. Rowan

doi:10.1021/cm903664g

Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides

Erik Schwartz, Eunhee Lim, Chandrakala M. Gowda, Andrea Liscio, Oliver Fenwick, Guoli Tu, Vincenzo Palermo, Rene De Gelder, Jeroen J.L.M. Cornelissen, Ernst R.H. Van Eck, Arno P.M. Kentgens, Franco Cacialli, Roeland J.M. Nolte, Paolo Samorì, Wilhelm T.S. Huck, Alan E. Rowan

Department of Applied Chemistry

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization of the isocyanide monomers onto various surfaces was carried out to give polymer brushes up to 150 nm thick. Insights into the electronic properties of the materials were obtained by Kelvin probe force microscopy (KPFM) and electroabsorption studies.

Original language	English
Pages (from-to)	2597-2607
Number of pages	11
Journal	Chemistry of Materials
Volume	22
Issue number	8
DOIs	https://doi.org/10.1021/cm903664g
State	Published - 27 Apr 2010

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Schwartz, E., Lim, E., Gowda, C. M., Liscio, A., Fenwick, O., Tu, G., Palermo, V., De Gelder, R., Cornelissen, J. J. L. M., Van Eck, E. R. H., Kentgens, A. P. M., Cacialli, F., Nolte, R. J. M., Samorì, P., Huck, W. T. S., & Rowan, A. E. (2010). Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides. Chemistry of Materials, 22(8), 2597-2607. https://doi.org/10.1021/cm903664g

@article{04af84d672364f4abefc6975b50e5933,

title = "Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides",

abstract = "We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization of the isocyanide monomers onto various surfaces was carried out to give polymer brushes up to 150 nm thick. Insights into the electronic properties of the materials were obtained by Kelvin probe force microscopy (KPFM) and electroabsorption studies.",

author = "Erik Schwartz and Eunhee Lim and Gowda, {Chandrakala M.} and Andrea Liscio and Oliver Fenwick and Guoli Tu and Vincenzo Palermo and {De Gelder}, Rene and Cornelissen, {Jeroen J.L.M.} and {Van Eck}, {Ernst R.H.} and Kentgens, {Arno P.M.} and Franco Cacialli and Nolte, {Roeland J.M.} and Paolo Samor{\`i} and Huck, {Wilhelm T.S.} and Rowan, {Alan E.}",

year = "2010",

month = apr,

day = "27",

doi = "10.1021/cm903664g",

language = "English",

volume = "22",

pages = "2597--2607",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society",

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Schwartz, E, Lim, E, Gowda, CM, Liscio, A, Fenwick, O, Tu, G, Palermo, V, De Gelder, R, Cornelissen, JJLM, Van Eck, ERH, Kentgens, APM, Cacialli, F, Nolte, RJM, Samorì, P, Huck, WTS & Rowan, AE 2010, 'Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides', Chemistry of Materials, vol. 22, no. 8, pp. 2597-2607. https://doi.org/10.1021/cm903664g

TY - JOUR

T1 - Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides

AU - Schwartz, Erik

AU - Lim, Eunhee

AU - Gowda, Chandrakala M.

AU - Liscio, Andrea

AU - Fenwick, Oliver

AU - Tu, Guoli

AU - Palermo, Vincenzo

AU - De Gelder, Rene

AU - Cornelissen, Jeroen J.L.M.

AU - Van Eck, Ernst R.H.

AU - Kentgens, Arno P.M.

AU - Cacialli, Franco

AU - Nolte, Roeland J.M.

AU - Samorì, Paolo

AU - Huck, Wilhelm T.S.

AU - Rowan, Alan E.

PY - 2010/4/27

Y1 - 2010/4/27

N2 - We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization of the isocyanide monomers onto various surfaces was carried out to give polymer brushes up to 150 nm thick. Insights into the electronic properties of the materials were obtained by Kelvin probe force microscopy (KPFM) and electroabsorption studies.

AB - We describe the design and synthesis of carbazole functionalized isocyanides and the detailed investigation of their properties. Characterization by solid state NMR, CD, and IR spectroscopic techniques reveals that the polymer has a well-defined helical architecture. Surface-initiated polymerization of the isocyanide monomers onto various surfaces was carried out to give polymer brushes up to 150 nm thick. Insights into the electronic properties of the materials were obtained by Kelvin probe force microscopy (KPFM) and electroabsorption studies.

UR - http://www.scopus.com/inward/record.url?scp=77951238383&partnerID=8YFLogxK

U2 - 10.1021/cm903664g

DO - 10.1021/cm903664g

M3 - Article

AN - SCOPUS:77951238383

SN - 0897-4756

VL - 22

SP - 2597

EP - 2607

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 8

ER -

Synthesis, characterization, and surface initiated polymerization of carbazole functionalized isocyanides

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