Synthesis of nanoporous material from zeolite USY and catalytic application to bio-oil conversion

Hyun Ju Park; Jong Ki Jeon; Ji Man Kim; Hyung Ik Lee; Jin Heong Yim; Junhong Park; Young Kwon Park

doi:10.1166/jnn.2008.1102

Synthesis of nanoporous material from zeolite USY and catalytic application to bio-oil conversion

Hyun Ju Park, Jong Ki Jeon, Ji Man Kim, Hyung Ik Lee, Jin Heong Yim, Junhong Park, Young Kwon Park

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

A highly ordered nanoporous aluminosilicate (MMZ _USY) was synthesized using commercially available zeolite USY as the framework source and cetyltrimethylammonium bromide as the template. The aluminosilicate was characterized by XRD, N ₂ adsorption, ICP-AES and TPD. The catalytic performance of the MMZ _USY material in the conversion of bio-oil was compared with that of Al-MCM-41, which was synthesized using a direct sol-gel method. The highly accessible nanopores, hydrothermal stability and the intermediate acidic properties of MMZ _USY correlated with the catalytic performance in the conversion of the bio-oil. The MMZ _USY used in this study showed excellent activity, selectivity and stability for the production of desirable organic compounds, such as phenolics, with a high degree of deoxygenation.

Original language	English
Pages (from-to)	5439-5444
Number of pages	6
Journal	Journal of Nanoscience and Nanotechnology
Volume	8
Issue number	10
DOIs	https://doi.org/10.1166/jnn.2008.1102
State	Published - Oct 2008

Keywords

Bio-oil
Catalytic conversion
Deoxygenation
Hydrothermal stability
Mmz
Phenolics

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10.1166/jnn.2008.1102

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title = "Synthesis of nanoporous material from zeolite USY and catalytic application to bio-oil conversion",

abstract = "A highly ordered nanoporous aluminosilicate (MMZ USY) was synthesized using commercially available zeolite USY as the framework source and cetyltrimethylammonium bromide as the template. The aluminosilicate was characterized by XRD, N 2 adsorption, ICP-AES and TPD. The catalytic performance of the MMZ USY material in the conversion of bio-oil was compared with that of Al-MCM-41, which was synthesized using a direct sol-gel method. The highly accessible nanopores, hydrothermal stability and the intermediate acidic properties of MMZ USY correlated with the catalytic performance in the conversion of the bio-oil. The MMZ USY used in this study showed excellent activity, selectivity and stability for the production of desirable organic compounds, such as phenolics, with a high degree of deoxygenation.",

keywords = "Bio-oil, Catalytic conversion, Deoxygenation, Hydrothermal stability, Mmz, Phenolics",

author = "Park, {Hyun Ju} and Jeon, {Jong Ki} and Kim, {Ji Man} and Lee, {Hyung Ik} and Yim, {Jin Heong} and Junhong Park and Park, {Young Kwon}",

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T1 - Synthesis of nanoporous material from zeolite USY and catalytic application to bio-oil conversion

AU - Park, Hyun Ju

AU - Jeon, Jong Ki

AU - Kim, Ji Man

AU - Lee, Hyung Ik

AU - Yim, Jin Heong

AU - Park, Junhong

AU - Park, Young Kwon

PY - 2008/10

Y1 - 2008/10

N2 - A highly ordered nanoporous aluminosilicate (MMZ USY) was synthesized using commercially available zeolite USY as the framework source and cetyltrimethylammonium bromide as the template. The aluminosilicate was characterized by XRD, N 2 adsorption, ICP-AES and TPD. The catalytic performance of the MMZ USY material in the conversion of bio-oil was compared with that of Al-MCM-41, which was synthesized using a direct sol-gel method. The highly accessible nanopores, hydrothermal stability and the intermediate acidic properties of MMZ USY correlated with the catalytic performance in the conversion of the bio-oil. The MMZ USY used in this study showed excellent activity, selectivity and stability for the production of desirable organic compounds, such as phenolics, with a high degree of deoxygenation.

AB - A highly ordered nanoporous aluminosilicate (MMZ USY) was synthesized using commercially available zeolite USY as the framework source and cetyltrimethylammonium bromide as the template. The aluminosilicate was characterized by XRD, N 2 adsorption, ICP-AES and TPD. The catalytic performance of the MMZ USY material in the conversion of bio-oil was compared with that of Al-MCM-41, which was synthesized using a direct sol-gel method. The highly accessible nanopores, hydrothermal stability and the intermediate acidic properties of MMZ USY correlated with the catalytic performance in the conversion of the bio-oil. The MMZ USY used in this study showed excellent activity, selectivity and stability for the production of desirable organic compounds, such as phenolics, with a high degree of deoxygenation.

KW - Bio-oil

KW - Catalytic conversion

KW - Deoxygenation

KW - Hydrothermal stability

KW - Mmz

KW - Phenolics

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SN - 1533-4880

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JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

IS - 10

ER -

Synthesis of nanoporous material from zeolite USY and catalytic application to bio-oil conversion

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Keywords

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