Synthesis of tricyclopentadiene over nanoporous MCM-41 catalysts

Eunseo Park; Jinhan Kim; Jin Heong Yim; Jeongsik Han; Young Kwon Park; Jong Ki Jeon

doi:10.1166/jnn.2015.10410

Synthesis of tricyclopentadiene over nanoporous MCM-41 catalysts

Eunseo Park, Jinhan Kim, Jin Heong Yim, Jeongsik Han, Young Kwon Park, Jong Ki Jeon

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The objective of this study is to evaluate the catalytic potential of metal oxide/MCM-41 catalysts in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization. Molybdenum oxide, tungsten oxide, and titanium oxide were loaded on MCM-41 using the modified atomic layer deposition method. The amount of the acid site with weak strength has been increased through metal oxide deposition. The oligomer yield in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization did not change with increasing of the amount of acid site. The highest tricyclopentadiene isomer selectivity over the MoO₃ / MCM-41 catalyst could be attributed to having the highest overall number of acid sites among the catalysts.

Original language	English
Pages (from-to)	5358-5361
Number of pages	4
Journal	Journal of Nanoscience and Nanotechnology
Volume	15
Issue number	7
DOIs	https://doi.org/10.1166/jnn.2015.10410
State	Published - 1 Jul 2015

Keywords

Dicyclopentadiene
Isomerization
MCM-41
Molybdenum oxide
Oligomerization

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10.1166/jnn.2015.10410

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title = "Synthesis of tricyclopentadiene over nanoporous MCM-41 catalysts",

abstract = "The objective of this study is to evaluate the catalytic potential of metal oxide/MCM-41 catalysts in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization. Molybdenum oxide, tungsten oxide, and titanium oxide were loaded on MCM-41 using the modified atomic layer deposition method. The amount of the acid site with weak strength has been increased through metal oxide deposition. The oligomer yield in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization did not change with increasing of the amount of acid site. The highest tricyclopentadiene isomer selectivity over the MoO3 / MCM-41 catalyst could be attributed to having the highest overall number of acid sites among the catalysts.",

keywords = "Dicyclopentadiene, Isomerization, MCM-41, Molybdenum oxide, Oligomerization",

author = "Eunseo Park and Jinhan Kim and Yim, {Jin Heong} and Jeongsik Han and Park, {Young Kwon} and Jeon, {Jong Ki}",

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doi = "10.1166/jnn.2015.10410",

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T1 - Synthesis of tricyclopentadiene over nanoporous MCM-41 catalysts

AU - Park, Eunseo

AU - Kim, Jinhan

AU - Yim, Jin Heong

AU - Han, Jeongsik

AU - Park, Young Kwon

AU - Jeon, Jong Ki

PY - 2015/7/1

Y1 - 2015/7/1

N2 - The objective of this study is to evaluate the catalytic potential of metal oxide/MCM-41 catalysts in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization. Molybdenum oxide, tungsten oxide, and titanium oxide were loaded on MCM-41 using the modified atomic layer deposition method. The amount of the acid site with weak strength has been increased through metal oxide deposition. The oligomer yield in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization did not change with increasing of the amount of acid site. The highest tricyclopentadiene isomer selectivity over the MoO3 / MCM-41 catalyst could be attributed to having the highest overall number of acid sites among the catalysts.

AB - The objective of this study is to evaluate the catalytic potential of metal oxide/MCM-41 catalysts in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization. Molybdenum oxide, tungsten oxide, and titanium oxide were loaded on MCM-41 using the modified atomic layer deposition method. The amount of the acid site with weak strength has been increased through metal oxide deposition. The oligomer yield in dicyclopentadiene oligomerization/dicyclopentadiene oligomer isomerization did not change with increasing of the amount of acid site. The highest tricyclopentadiene isomer selectivity over the MoO3 / MCM-41 catalyst could be attributed to having the highest overall number of acid sites among the catalysts.

KW - Dicyclopentadiene

KW - Isomerization

KW - MCM-41

KW - Molybdenum oxide

KW - Oligomerization

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U2 - 10.1166/jnn.2015.10410

DO - 10.1166/jnn.2015.10410

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JO - Journal of Nanoscience and Nanotechnology

JF - Journal of Nanoscience and Nanotechnology

IS - 7

ER -

Synthesis of tricyclopentadiene over nanoporous MCM-41 catalysts

Abstract

Keywords

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