The hydrodeoxygenation of 2-methoxyphenol over Ni/Kieselguhr catalysts as a model reaction for bio-oil upgrading

J. K. Jeon; B. Huh; C. H. Lee; D. J. Suh; Y. W. Suh; H. S. Heo; Y. K. Park

doi:10.1080/15567036.2010.511427

The hydrodeoxygenation of 2-methoxyphenol over Ni/Kieselguhr catalysts as a model reaction for bio-oil upgrading

J. K. Jeon, B. Huh, C. H. Lee, D. J. Suh, Y. W. Suh, H. S. Heo, Y. K. Park

School of Environmental Engineering

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Ni/kieselguhr catalysts were applied to hydrodeoxygenate 2-methoxyphenol as a model reaction for bio-oil upgrading in a batch reactor at 100°C and 1.36 MPa. The Ni(40 wt%)-MgO(1.8 wt%)/kieselguhr showed much higher activity in the 2-methoxyphenol hydrodeoxygenation, which could be attributed to the optimal nickel particle size, surface area, and reducibility of the catalyst. Of the Na₂CO₃+Urea, NaHCO₃, and .NH₄/2CO₃ precipitants, the Na₂CO₃ C Urea showed the highest activity because the dispersion and surface area of nickel, rather than the pore size of the catalyst, seems to play an important role in the 2-methoxyphenol hydrodeoxygenation.

Original language	English
Pages (from-to)	271-277
Number of pages	7
Journal	Energy Sources, Part A: Recovery, Utilization and Environmental Effects
Volume	35
Issue number	3
DOIs	https://doi.org/10.1080/15567036.2010.511427
State	Published - 2013

Keywords

2-methoxyphenol
Bio-oil
Hydrodeoxygenation
MgO
Ni/kieselguhr

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1080/15567036.2010.511427

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@article{c484434e362240c39aae509409679397,

title = "The hydrodeoxygenation of 2-methoxyphenol over Ni/Kieselguhr catalysts as a model reaction for bio-oil upgrading",

abstract = "Ni/kieselguhr catalysts were applied to hydrodeoxygenate 2-methoxyphenol as a model reaction for bio-oil upgrading in a batch reactor at 100°C and 1.36 MPa. The Ni(40 wt\%)-MgO(1.8 wt\%)/kieselguhr showed much higher activity in the 2-methoxyphenol hydrodeoxygenation, which could be attributed to the optimal nickel particle size, surface area, and reducibility of the catalyst. Of the Na2CO3+Urea, NaHCO3, and .NH4/2CO3 precipitants, the Na2CO3 C Urea showed the highest activity because the dispersion and surface area of nickel, rather than the pore size of the catalyst, seems to play an important role in the 2-methoxyphenol hydrodeoxygenation.",

keywords = "2-methoxyphenol, Bio-oil, Hydrodeoxygenation, MgO, Ni/kieselguhr",

author = "Jeon, \{J. K.\} and B. Huh and Lee, \{C. H.\} and Suh, \{D. J.\} and Suh, \{Y. W.\} and Heo, \{H. S.\} and Park, \{Y. K.\}",

year = "2013",

doi = "10.1080/15567036.2010.511427",

language = "English",

volume = "35",

pages = "271--277",

journal = "Energy Sources, Part A: Recovery, Utilization and Environmental Effects",

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TY - JOUR

T1 - The hydrodeoxygenation of 2-methoxyphenol over Ni/Kieselguhr catalysts as a model reaction for bio-oil upgrading

AU - Jeon, J. K.

AU - Huh, B.

AU - Lee, C. H.

AU - Suh, D. J.

AU - Suh, Y. W.

AU - Heo, H. S.

AU - Park, Y. K.

PY - 2013

Y1 - 2013

N2 - Ni/kieselguhr catalysts were applied to hydrodeoxygenate 2-methoxyphenol as a model reaction for bio-oil upgrading in a batch reactor at 100°C and 1.36 MPa. The Ni(40 wt%)-MgO(1.8 wt%)/kieselguhr showed much higher activity in the 2-methoxyphenol hydrodeoxygenation, which could be attributed to the optimal nickel particle size, surface area, and reducibility of the catalyst. Of the Na2CO3+Urea, NaHCO3, and .NH4/2CO3 precipitants, the Na2CO3 C Urea showed the highest activity because the dispersion and surface area of nickel, rather than the pore size of the catalyst, seems to play an important role in the 2-methoxyphenol hydrodeoxygenation.

AB - Ni/kieselguhr catalysts were applied to hydrodeoxygenate 2-methoxyphenol as a model reaction for bio-oil upgrading in a batch reactor at 100°C and 1.36 MPa. The Ni(40 wt%)-MgO(1.8 wt%)/kieselguhr showed much higher activity in the 2-methoxyphenol hydrodeoxygenation, which could be attributed to the optimal nickel particle size, surface area, and reducibility of the catalyst. Of the Na2CO3+Urea, NaHCO3, and .NH4/2CO3 precipitants, the Na2CO3 C Urea showed the highest activity because the dispersion and surface area of nickel, rather than the pore size of the catalyst, seems to play an important role in the 2-methoxyphenol hydrodeoxygenation.

KW - 2-methoxyphenol

KW - Bio-oil

KW - Hydrodeoxygenation

KW - MgO

KW - Ni/kieselguhr

UR - https://www.scopus.com/pages/publications/84949750420

U2 - 10.1080/15567036.2010.511427

DO - 10.1080/15567036.2010.511427

M3 - Article

AN - SCOPUS:84949750420

SN - 1556-7036

VL - 35

SP - 271

EP - 277

JO - Energy Sources, Part A: Recovery, Utilization and Environmental Effects

JF - Energy Sources, Part A: Recovery, Utilization and Environmental Effects

IS - 3

ER -

The hydrodeoxygenation of 2-methoxyphenol over Ni/Kieselguhr catalysts as a model reaction for bio-oil upgrading

Abstract

Keywords

UN SDGs

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