Using CO₂ as an Oxidant in the Catalytic Pyrolysis of Peat Moss from the North Polar Region

As global warming and climate change become perceived as significant, the release of greenhouse gases (GHGs) stored in the earth's polar regions is considered a matter of concern. Here, we focused on exploiting GHGs to address potential global warming challenges in the north polar regions. In particular, we used CO₂ as a soft oxidant to recover energy as syngas (CO and H₂) and to produce biochars from pyrolysis of peat moss. CO₂ expedited homogeneous reaction with volatile matters from peat moss pyrolysis, and the mechanistic CO₂ role resulted in the conversion of CO₂ and peat moss to CO at ≥530 °C. Steel slag waste was then used as an ex situ catalyst to increase reaction kinetics, addressing the issue of the role of CO₂ being limited to ≥530 °C, with the result where substantial H₂ and CO formation was achieved at a milder temperature. The porosity of biochars, a solid peat moss pyrolysis product, was modified in the presence of CO₂, with a significant improvement in CO₂ adsorption capacity compared to those achieved by N₂ pyrolysis. Therefore, CO₂ has the potential to serve as an initial feedstock in sustainable biomass-to-energy applications and biochar production, mitigating atmospheric carbon concentrations.